Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents

J. N. Spencer, J. E. Mihalick, T. J. Nicholson, P. A. Cortina, J. L. Rinehimer, J. E. Smith, Xiaoming Ke, Qing He, S. E. Daniels, Shaym Puppala, James L. Ealy, L. J. Fenton, William J. Nicholson, Ian Paul, Claude H. Yoder

Research output: Contribution to journalArticle

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Abstract

Equilibrium constants and enthalpies of host-guest complexation have been determined by calorimetry for cyclic and acyclic polyether hosts with a variety of guests and solvents. The thermodynamic parameters for complexation of group I cation guests by crown ethers in water solvent may be correlated to the hydration enthalpy and relative sizes of cation and ether. The macrocyclic effect is observed for cation-ether systems in water solvent but not for the complexation of malononitrile by ethers in nonpolar aromatic or alcohol solvent.

Original languageEnglish (US)
Pages (from-to)10509-10512
Number of pages4
JournalJournal of physical chemistry
Volume97
Issue number40
DOIs
StatePublished - Jan 1 1993

Fingerprint

Ether
Organic solvents
Ethers
ethers
Complexation
Cations
Positive ions
cations
Enthalpy
enthalpy
malononitrile
Crown Ethers
Crown ethers
Water
Polyethers
Equilibrium constants
Calorimetry
Hydration
water
hydration

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physical and Theoretical Chemistry

Cite this

Spencer, J. N., Mihalick, J. E., Nicholson, T. J., Cortina, P. A., Rinehimer, J. L., Smith, J. E., ... Yoder, C. H. (1993). Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents. Journal of physical chemistry, 97(40), 10509-10512. https://doi.org/10.1021/j100142a040
Spencer, J. N. ; Mihalick, J. E. ; Nicholson, T. J. ; Cortina, P. A. ; Rinehimer, J. L. ; Smith, J. E. ; Ke, Xiaoming ; He, Qing ; Daniels, S. E. ; Puppala, Shaym ; Ealy, James L. ; Fenton, L. J. ; Nicholson, William J. ; Paul, Ian ; Yoder, Claude H. / Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents. In: Journal of physical chemistry. 1993 ; Vol. 97, No. 40. pp. 10509-10512.
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author = "Spencer, {J. N.} and Mihalick, {J. E.} and Nicholson, {T. J.} and Cortina, {P. A.} and Rinehimer, {J. L.} and Smith, {J. E.} and Xiaoming Ke and Qing He and Daniels, {S. E.} and Shaym Puppala and Ealy, {James L.} and Fenton, {L. J.} and Nicholson, {William J.} and Ian Paul and Yoder, {Claude H.}",
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Spencer, JN, Mihalick, JE, Nicholson, TJ, Cortina, PA, Rinehimer, JL, Smith, JE, Ke, X, He, Q, Daniels, SE, Puppala, S, Ealy, JL, Fenton, LJ, Nicholson, WJ, Paul, I & Yoder, CH 1993, 'Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents', Journal of physical chemistry, vol. 97, no. 40, pp. 10509-10512. https://doi.org/10.1021/j100142a040

Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents. / Spencer, J. N.; Mihalick, J. E.; Nicholson, T. J.; Cortina, P. A.; Rinehimer, J. L.; Smith, J. E.; Ke, Xiaoming; He, Qing; Daniels, S. E.; Puppala, Shaym; Ealy, James L.; Fenton, L. J.; Nicholson, William J.; Paul, Ian; Yoder, Claude H.

In: Journal of physical chemistry, Vol. 97, No. 40, 01.01.1993, p. 10509-10512.

Research output: Contribution to journalArticle

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AU - Spencer, J. N.

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AU - Ealy, James L.

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AU - Paul, Ian

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Spencer JN, Mihalick JE, Nicholson TJ, Cortina PA, Rinehimer JL, Smith JE et al. Comparison of the macrocyclic effect for ether hosts in aqueous and organic solvents. Journal of physical chemistry. 1993 Jan 1;97(40):10509-10512. https://doi.org/10.1021/j100142a040