Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

Mark Maroncelli, Graham R. Fleming

Research output: Contribution to journalReview article

106 Scopus citations

Abstract

The results of time-resolved Stokes shift measurements are compared to a molecular theory of ionic solvation dynamics recently solved by Rips, Klafter, and Jortner [J. Chem. Phys. 88, 3246 (1988)]. Although the theoretical predictions show only semiquantitative agreement with experiment, this molecularly based model provides a satisfying framework for understanding the large departures observed from the behavior predicted by simple continuum treatments of solvation dynamics.

Original languageEnglish (US)
Pages (from-to)875-881
Number of pages7
JournalThe Journal of chemical physics
Volume89
Issue number2
DOIs
StatePublished - 1988

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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