Comparison of two- and three-layer restacked Dion-Jacobson phase niobate nanosheets as catalysts for photochemical hydrogen evolution

Kazuhiko Maeda, Thomas E. Mallouk

Research output: Contribution to journalArticle

91 Citations (Scopus)

Abstract

Restacked niobate nanosheets were prepared by exfoliation of the corresponding Dion-Jacobson type layered perovskites (HCa2Nb 3O10, HSr2Nb3O10 and HLaNb2O7) with tetra(n-butyl)ammonium hydroxide and subsequent treatment with hydrochloric acid. The nanosheets were characterized by means of X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and diffuse reflectance spectroscopy. With modification by platinum nanoparticles as additional catalysts, these nanosheet materials were tested as photocatalysts for hydrogen evolution from water containing 2-propanol as an electron donor under ultraviolet irradiation (λ > 300 nm). The activity of a triple-layered nanosheet (HSr2Nb3O 10) was an order of magnitude higher than that of the HLaNb 2O7 nanosheet with double perovskite layers, despite their physicochemical similarity. Physicochemical analyses suggested that in triple-layered perovskite nanosheets, photocatalytic activity is influenced by several factors including the conduction band potential and the band-gap energy (the number of available photons), which are derived from the distortion of perovskite blocks consisting of NbO6 octahedra.

Original languageEnglish (US)
Pages (from-to)4813-4818
Number of pages6
JournalJournal of Materials Chemistry
Volume19
Issue number27
DOIs
StatePublished - Jul 9 2009

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Nanosheets
Hydrogen
Catalysts
Perovskite
Ammonium Hydroxide
Ammonium hydroxide
2-Propanol
Hydrochloric Acid
Propanol
Hydrochloric acid
Photocatalysts
Platinum
Conduction bands
Raman spectroscopy
Energy gap
Photons
Irradiation
Spectroscopy
Nanoparticles
X ray diffraction

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Chemistry

Cite this

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abstract = "Restacked niobate nanosheets were prepared by exfoliation of the corresponding Dion-Jacobson type layered perovskites (HCa2Nb 3O10, HSr2Nb3O10 and HLaNb2O7) with tetra(n-butyl)ammonium hydroxide and subsequent treatment with hydrochloric acid. The nanosheets were characterized by means of X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and diffuse reflectance spectroscopy. With modification by platinum nanoparticles as additional catalysts, these nanosheet materials were tested as photocatalysts for hydrogen evolution from water containing 2-propanol as an electron donor under ultraviolet irradiation (λ > 300 nm). The activity of a triple-layered nanosheet (HSr2Nb3O 10) was an order of magnitude higher than that of the HLaNb 2O7 nanosheet with double perovskite layers, despite their physicochemical similarity. Physicochemical analyses suggested that in triple-layered perovskite nanosheets, photocatalytic activity is influenced by several factors including the conduction band potential and the band-gap energy (the number of available photons), which are derived from the distortion of perovskite blocks consisting of NbO6 octahedra.",
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Comparison of two- and three-layer restacked Dion-Jacobson phase niobate nanosheets as catalysts for photochemical hydrogen evolution. / Maeda, Kazuhiko; Mallouk, Thomas E.

In: Journal of Materials Chemistry, Vol. 19, No. 27, 09.07.2009, p. 4813-4818.

Research output: Contribution to journalArticle

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