COMPLEX FORMATION, CONDUCTIVITY AND LITHIUM ION TRANSPORT IN POLYPHOSPHAZENE-BASED SOLID ELECTROLYTES.

Peter Miller Blonsky, Duward F. Shriver, P. Austin, Harry R. Allcock

Research output: Chapter in Book/Report/Conference proceedingConference contribution

30 Scopus citations

Abstract

A new polymer poly left bracket bis-(methoxyethoxyethoxide)phosphazene right bracket , MEEP, was synthesized. It forms complexes with a wide variety of salts. The conductivity and lithium ion transport numbers for a variety of lithium salts complexed with MEEP are reported in this paper. For most electrochemical applications, a polymer electrolyte should have a high conductivity at room temperature. The MEEP based system exhibits room temperature conductivities which are 2-3 orders of magnitude better than the corresponding PEO based electrolytes.

Original languageEnglish (US)
Title of host publicationPolymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material
PublisherACS
Pages118-122
Number of pages5
Volume53
ISBN (Print)0841208832
StatePublished - 1985

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All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Blonsky, P. M., Shriver, D. F., Austin, P., & Allcock, H. R. (1985). COMPLEX FORMATION, CONDUCTIVITY AND LITHIUM ION TRANSPORT IN POLYPHOSPHAZENE-BASED SOLID ELECTROLYTES. In Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material (Vol. 53, pp. 118-122). ACS.