Composites of 0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO3 prepared by a sol-gel method

Effect of atmosphere powders

Dong Soo Paik, Sridhar Komarneni

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Dielectric and electrical properties of relaxor ferroelectric 0.9PMN-0.1PT ceramics prepared by a sol-gel method were investigated as a function of PbZrO3 atmosphere powders. The proper amount of atmosphere powders led to better properties of dielectric constant, polarization, and strain by preventing PbO volatilization from ceramics. Excessive amount of atmosphere powder, however, resulted in aging characteristics such as decreases in dielectric constant and loss exhibiting saddle-shaped dielectric constant and loss vs. temperature curves. A propeller-shaped P-E hysteresis curve indicating aging characteristics was also observed when an excessive amount of atmosphere powder was used during sintering. The aging of ceramics caused by absorption of PbO into the ceramics resulted in decreased polarization and strain. These aging characteristics associated with defects by excessive PbO absorption could not be reversed even though the aged ceramics underwent a heat-treatment above the dielectric maximum temperature.

Original languageEnglish (US)
Pages (from-to)2313-2317
Number of pages5
JournalJournal of Materials Science
Volume34
Issue number10
DOIs
StatePublished - Jan 1 1999

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Powders
Sol-gel process
Aging of materials
Permittivity
Composite materials
Dielectric losses
Polarization
Propellers
Vaporization
Dielectric properties
Ferroelectric materials
Hysteresis
Electric properties
Sintering
Heat treatment
Temperature
Defects

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

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abstract = "Dielectric and electrical properties of relaxor ferroelectric 0.9PMN-0.1PT ceramics prepared by a sol-gel method were investigated as a function of PbZrO3 atmosphere powders. The proper amount of atmosphere powders led to better properties of dielectric constant, polarization, and strain by preventing PbO volatilization from ceramics. Excessive amount of atmosphere powder, however, resulted in aging characteristics such as decreases in dielectric constant and loss exhibiting saddle-shaped dielectric constant and loss vs. temperature curves. A propeller-shaped P-E hysteresis curve indicating aging characteristics was also observed when an excessive amount of atmosphere powder was used during sintering. The aging of ceramics caused by absorption of PbO into the ceramics resulted in decreased polarization and strain. These aging characteristics associated with defects by excessive PbO absorption could not be reversed even though the aged ceramics underwent a heat-treatment above the dielectric maximum temperature.",
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Composites of 0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO3 prepared by a sol-gel method : Effect of atmosphere powders. / Paik, Dong Soo; Komarneni, Sridhar.

In: Journal of Materials Science, Vol. 34, No. 10, 01.01.1999, p. 2313-2317.

Research output: Contribution to journalArticle

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AB - Dielectric and electrical properties of relaxor ferroelectric 0.9PMN-0.1PT ceramics prepared by a sol-gel method were investigated as a function of PbZrO3 atmosphere powders. The proper amount of atmosphere powders led to better properties of dielectric constant, polarization, and strain by preventing PbO volatilization from ceramics. Excessive amount of atmosphere powder, however, resulted in aging characteristics such as decreases in dielectric constant and loss exhibiting saddle-shaped dielectric constant and loss vs. temperature curves. A propeller-shaped P-E hysteresis curve indicating aging characteristics was also observed when an excessive amount of atmosphere powder was used during sintering. The aging of ceramics caused by absorption of PbO into the ceramics resulted in decreased polarization and strain. These aging characteristics associated with defects by excessive PbO absorption could not be reversed even though the aged ceramics underwent a heat-treatment above the dielectric maximum temperature.

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