Conformational Analysis of Poly(dihalophosphazenes)

Harry R. Allcock, R. W. Allen, J. J. Meister

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The poly(dihalophosphazenes), (NPF2)n, (NPCl2)n, and (NPBr2)n, have been examined by conformational analysis using nonbonding intramolecular interactions based on a 6:12 Lennard-Jones potential and a Coulombic term. The results provide an insight into the reasons for the low glass transition temperatures, the high chain flexibilities, and the conformational preferences of these molecules.

Original languageEnglish (US)
Pages (from-to)950-955
Number of pages6
JournalMacromolecules
Volume9
Issue number6
DOIs
StatePublished - Nov 1 1976

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Lennard-Jones potential
Molecules
Glass transition temperature

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Allcock, Harry R. ; Allen, R. W. ; Meister, J. J. / Conformational Analysis of Poly(dihalophosphazenes). In: Macromolecules. 1976 ; Vol. 9, No. 6. pp. 950-955.
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Conformational Analysis of Poly(dihalophosphazenes). / Allcock, Harry R.; Allen, R. W.; Meister, J. J.

In: Macromolecules, Vol. 9, No. 6, 01.11.1976, p. 950-955.

Research output: Contribution to journalArticle

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