Abstract
A room-temperature solution route to the controlled synthesis of 0-, 1-, 2-, and 3-D assemblies of molecularly linked metal chalcogenide clusters using essentially identical building blocks is reported. The solvating, ligating, and reducing abilities of hydrazine at room temperature have been exploited to simultaneously dissolve metal chalcogenides and organize the resulting building blocks into frameworks of increasing dimensionalities. Control of the product dimensionality was achieved by varying the reactant ratios and the amount of hydrazine solvent employed in the reaction. The products have been characterized by single-crystal X-ray diffraction, Raman spectroscopy, and magnetic susceptibility.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 7238-7240 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 46 |
| Issue number | 18 |
| DOIs | |
| State | Published - Sep 3 2007 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Controlled assembly of zero-, one-, two-, and three-dimensional metal chalcogenide structures. / Yuan, Min; Dirmyer, Matthew; Badding, John V.; Sen, Ayusman; Dahlberg, Maria; Schiffer, Peter.
In: Inorganic Chemistry, Vol. 46, No. 18, 03.09.2007, p. 7238-7240.Research output: Contribution to journal › Article
TY - JOUR
T1 - Controlled assembly of zero-, one-, two-, and three-dimensional metal chalcogenide structures
AU - Yuan, Min
AU - Dirmyer, Matthew
AU - Badding, John V.
AU - Sen, Ayusman
AU - Dahlberg, Maria
AU - Schiffer, Peter
PY - 2007/9/3
Y1 - 2007/9/3
N2 - A room-temperature solution route to the controlled synthesis of 0-, 1-, 2-, and 3-D assemblies of molecularly linked metal chalcogenide clusters using essentially identical building blocks is reported. The solvating, ligating, and reducing abilities of hydrazine at room temperature have been exploited to simultaneously dissolve metal chalcogenides and organize the resulting building blocks into frameworks of increasing dimensionalities. Control of the product dimensionality was achieved by varying the reactant ratios and the amount of hydrazine solvent employed in the reaction. The products have been characterized by single-crystal X-ray diffraction, Raman spectroscopy, and magnetic susceptibility.
AB - A room-temperature solution route to the controlled synthesis of 0-, 1-, 2-, and 3-D assemblies of molecularly linked metal chalcogenide clusters using essentially identical building blocks is reported. The solvating, ligating, and reducing abilities of hydrazine at room temperature have been exploited to simultaneously dissolve metal chalcogenides and organize the resulting building blocks into frameworks of increasing dimensionalities. Control of the product dimensionality was achieved by varying the reactant ratios and the amount of hydrazine solvent employed in the reaction. The products have been characterized by single-crystal X-ray diffraction, Raman spectroscopy, and magnetic susceptibility.
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U2 - 10.1021/ic7007107
DO - 10.1021/ic7007107
M3 - Article
VL - 46
SP - 7238
EP - 7240
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 18
ER -