Controlled assembly of zero-, one-, two-, and three-dimensional metal chalcogenide structures

Min Yuan, Matthew Dirmyer, John V. Badding, Ayusman Sen, Maria Dahlberg, Peter Schiffer

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

A room-temperature solution route to the controlled synthesis of 0-, 1-, 2-, and 3-D assemblies of molecularly linked metal chalcogenide clusters using essentially identical building blocks is reported. The solvating, ligating, and reducing abilities of hydrazine at room temperature have been exploited to simultaneously dissolve metal chalcogenides and organize the resulting building blocks into frameworks of increasing dimensionalities. Control of the product dimensionality was achieved by varying the reactant ratios and the amount of hydrazine solvent employed in the reaction. The products have been characterized by single-crystal X-ray diffraction, Raman spectroscopy, and magnetic susceptibility.

Original languageEnglish (US)
Pages (from-to)7238-7240
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number18
DOIs
StatePublished - Sep 3 2007

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hydrazine
hydrazines
assembly
Metals
Chalcogenides
chalcogenides
room temperature
metal clusters
products
Magnetic susceptibility
metals
assemblies
Raman spectroscopy
routes
Single crystals
magnetic permeability
X ray diffraction
Temperature
single crystals
synthesis

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Yuan, Min ; Dirmyer, Matthew ; Badding, John V. ; Sen, Ayusman ; Dahlberg, Maria ; Schiffer, Peter. / Controlled assembly of zero-, one-, two-, and three-dimensional metal chalcogenide structures. In: Inorganic Chemistry. 2007 ; Vol. 46, No. 18. pp. 7238-7240.
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Yuan, M, Dirmyer, M, Badding, JV, Sen, A, Dahlberg, M & Schiffer, P 2007, 'Controlled assembly of zero-, one-, two-, and three-dimensional metal chalcogenide structures', Inorganic Chemistry, vol. 46, no. 18, pp. 7238-7240. https://doi.org/10.1021/ic7007107

Controlled assembly of zero-, one-, two-, and three-dimensional metal chalcogenide structures. / Yuan, Min; Dirmyer, Matthew; Badding, John V.; Sen, Ayusman; Dahlberg, Maria; Schiffer, Peter.

In: Inorganic Chemistry, Vol. 46, No. 18, 03.09.2007, p. 7238-7240.

Research output: Contribution to journalArticle

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