Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides

Surendra Thapa, Prakash Basnet, Santosh K. Gurung, Ramesh Giri

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

An unprecedented CuI-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides is reported. Mechanistic studies with a Cp2ZrAr2 complex revealed that Cp2Zr(Ar)(Cl) is the reactive species that undergoes transmetalation with (PN-1)CuI. In addition, experiments with radical probes indicated that the reaction proceeds via a non-radical pathway. This journal is

Original languageEnglish (US)
Pages (from-to)4009-4012
Number of pages4
JournalChemical Communications
Volume51
Issue number19
DOIs
StatePublished - Mar 7 2015

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Iodides
Copper
Experiments

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Thapa, Surendra ; Basnet, Prakash ; Gurung, Santosh K. ; Giri, Ramesh. / Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides. In: Chemical Communications. 2015 ; Vol. 51, No. 19. pp. 4009-4012.
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Copper-catalysed cross-coupling of arylzirconium reagents with aryl and heteroaryl iodides. / Thapa, Surendra; Basnet, Prakash; Gurung, Santosh K.; Giri, Ramesh.

In: Chemical Communications, Vol. 51, No. 19, 07.03.2015, p. 4009-4012.

Research output: Contribution to journalArticle

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AU - Thapa, Surendra

AU - Basnet, Prakash

AU - Gurung, Santosh K.

AU - Giri, Ramesh

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