TY - JOUR
T1 - Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode
AU - Yan, Pengfei
AU - Zheng, Jianming
AU - Chen, Tianwu
AU - Luo, Langli
AU - Jiang, Yuyuan
AU - Wang, Kuan
AU - Sui, Manling
AU - Zhang, Ji Guang
AU - Zhang, Sulin
AU - Wang, Chongmin
N1 - Funding Information:
This work is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the U.S. Department of Energy (DOE) under Contract no. DE-AC02-05CH11231, Subcontract no. 18769 and no. 6951379 under the Advanced Battery Materials Research program. Microscopic analyses were conducted in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the Department of Energy under Contract DE-AC05-76RLO1830. P.Y. and M.S. thank the Chinese National Natural Science Fund for Innovative Research Groups (Grant no. 51621003) and the National Key Research and Development Program of China (Grant no. 2016YFB0700700). T.C. and S.Z. acknowledge the support by the National Science Foundation through the projects CMMI-0900692, DMR-1610430, and ECCS-1610331.
Funding Information:
This work is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the U.S. Department of Energy (DOE) under Contract no. DE-AC02-05CH11231, Subcontract no. 18769 and no. 6951379 under the Advanced Battery Materials Research program. Microscopic analyses were conducted in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by DOE's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the Department of Energy under Contract DE-AC05- 76RLO1830. P.Y. and M.S. thank the Chinese National Natural Science Fund for Innovative Research Groups (Grant no. 51621003) and the National Key Research and Development Program of China (Grant no. 2016YFB0700700). T.C. and S.Z. acknowledge the support by the National Science Foundation through the projects CMMI- 0900692, DMR-1610430, and ECCS-1610331
Publisher Copyright:
© 2018 The Author(s).
PY - 2018/12/1
Y1 - 2018/12/1
N2 - Electrochemically driven functioning of a battery inevitably induces thermal and mechanical effects, which in turn couple with the electrochemical effect and collectively govern the performance of the battery. However, such a coupling effect, whether favorable or detrimental, has never been explicitly elucidated. Here we use in situ transmission electron microscopy to demonstrate such a coupling effect. We discover that thermally perturbating delithiated LiNi0.6Mn0.2Co0.2O2 will trigger explosive nucleation and propagation of intragranular cracks in the lattice, providing us a unique opportunity to directly visualize the cracking mechanism and dynamics. We reveal that thermal stress associated with electrochemically induced phase inhomogeneity and internal pressure resulting from oxygen release are the primary driving forces for intragranular cracking that resembles a "popcorn" fracture mechanism. The present work reveals that, for battery performance, the intricate coupling of electrochemical, thermal, and mechanical effects will surpass the superposition of individual effects.
AB - Electrochemically driven functioning of a battery inevitably induces thermal and mechanical effects, which in turn couple with the electrochemical effect and collectively govern the performance of the battery. However, such a coupling effect, whether favorable or detrimental, has never been explicitly elucidated. Here we use in situ transmission electron microscopy to demonstrate such a coupling effect. We discover that thermally perturbating delithiated LiNi0.6Mn0.2Co0.2O2 will trigger explosive nucleation and propagation of intragranular cracks in the lattice, providing us a unique opportunity to directly visualize the cracking mechanism and dynamics. We reveal that thermal stress associated with electrochemically induced phase inhomogeneity and internal pressure resulting from oxygen release are the primary driving forces for intragranular cracking that resembles a "popcorn" fracture mechanism. The present work reveals that, for battery performance, the intricate coupling of electrochemical, thermal, and mechanical effects will surpass the superposition of individual effects.
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U2 - 10.1038/s41467-018-04862-w
DO - 10.1038/s41467-018-04862-w
M3 - Article
C2 - 29934582
AN - SCOPUS:85048971010
SN - 2041-1723
VL - 9
JO - Nature Communications
JF - Nature Communications
IS - 1
M1 - 2437
ER -