Cross-linked hydroxide conductive membranes with side chains for direct methanol fuel cell applications

Shuai Xu, Gang Zhang, Yang Zhang, Chengji Zhao, Liyuan Zhang, Mingyu Li, Jing Wang, Na Zhang, Hui Na

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

A series of novel poly(ether ether ketone) copolymers containing methyl groups on the side chain were prepared based on a new monomer (3,4-dimethyl)phenylhydroquinone. Then a series of hydroxide exchange membranes with different IEC values were obtained through bromination and quaternary amination of the copolymers. By adjusting the contents of methyl groups in the copolymers, we could control the final structures of the membranes. The chemical structures of the monomers and copolymers were analyzed by 1H NMR spectroscopy. After that, for the purpose of enhancing the dimensional stability and methanol resistance of the membrane, we prepared cross-linked membranes through a Friedel-Crafts reaction between bromomethyl groups and aromatic rings. The properties of the membranes related to fuel cell application were evaluated in detail. All the membranes showed good thermal and mechanical stabilities and conductivities. Moreover, the cross-linked membranes exhibit better dimensional stabilities and selectivities. Among those membranes, xPEEK-Q-100 showed a high conductivity (0.036 S cm -1 at 80 °C), a low swelling ratio of 6.6% and a methanol permeation coefficient of 2.9 × 10 -7 cm 2 s -1. The outstanding properties indicated that the application of PEEK-Q-xx membranes in fuel cells was promising.

Original languageEnglish (US)
Pages (from-to)13295-13302
Number of pages8
JournalJournal of Materials Chemistry
Volume22
Issue number26
DOIs
StatePublished - Jul 14 2012

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Direct methanol fuel cells (DMFC)
Membranes
Copolymers
Polyether ether ketones
Dimensional stability
Methanol
Fuel cells
Monomers
Friedel-Crafts reaction
hydroxide ion
Amination
Mechanical stability
Permeation
Nuclear magnetic resonance spectroscopy
Swelling
Thermodynamic stability

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Chemistry

Cite this

Xu, Shuai ; Zhang, Gang ; Zhang, Yang ; Zhao, Chengji ; Zhang, Liyuan ; Li, Mingyu ; Wang, Jing ; Zhang, Na ; Na, Hui. / Cross-linked hydroxide conductive membranes with side chains for direct methanol fuel cell applications. In: Journal of Materials Chemistry. 2012 ; Vol. 22, No. 26. pp. 13295-13302.
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abstract = "A series of novel poly(ether ether ketone) copolymers containing methyl groups on the side chain were prepared based on a new monomer (3,4-dimethyl)phenylhydroquinone. Then a series of hydroxide exchange membranes with different IEC values were obtained through bromination and quaternary amination of the copolymers. By adjusting the contents of methyl groups in the copolymers, we could control the final structures of the membranes. The chemical structures of the monomers and copolymers were analyzed by 1H NMR spectroscopy. After that, for the purpose of enhancing the dimensional stability and methanol resistance of the membrane, we prepared cross-linked membranes through a Friedel-Crafts reaction between bromomethyl groups and aromatic rings. The properties of the membranes related to fuel cell application were evaluated in detail. All the membranes showed good thermal and mechanical stabilities and conductivities. Moreover, the cross-linked membranes exhibit better dimensional stabilities and selectivities. Among those membranes, xPEEK-Q-100 showed a high conductivity (0.036 S cm -1 at 80 °C), a low swelling ratio of 6.6{\%} and a methanol permeation coefficient of 2.9 × 10 -7 cm 2 s -1. The outstanding properties indicated that the application of PEEK-Q-xx membranes in fuel cells was promising.",
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Xu, S, Zhang, G, Zhang, Y, Zhao, C, Zhang, L, Li, M, Wang, J, Zhang, N & Na, H 2012, 'Cross-linked hydroxide conductive membranes with side chains for direct methanol fuel cell applications', Journal of Materials Chemistry, vol. 22, no. 26, pp. 13295-13302. https://doi.org/10.1039/c2jm16593g

Cross-linked hydroxide conductive membranes with side chains for direct methanol fuel cell applications. / Xu, Shuai; Zhang, Gang; Zhang, Yang; Zhao, Chengji; Zhang, Liyuan; Li, Mingyu; Wang, Jing; Zhang, Na; Na, Hui.

In: Journal of Materials Chemistry, Vol. 22, No. 26, 14.07.2012, p. 13295-13302.

Research output: Contribution to journalArticle

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AU - Xu, Shuai

AU - Zhang, Gang

AU - Zhang, Yang

AU - Zhao, Chengji

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AU - Li, Mingyu

AU - Wang, Jing

AU - Zhang, Na

AU - Na, Hui

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