Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin- 4-one

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Abstract

In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one-κO)triphenyltin(IV), [Sn(C 6 H 5 ) 3 Cl(C 15 H 19 NOS)], the tin(IV) atom exhibits a trigonal-bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O - Sn - Cl = 175.07 (14) °]. The thiazolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9) ° with respect to the pendant C-phenyl plane and 34.3 (11) ° to the N-cyclohexyl ring (all atoms). The C-phenyl and N-cyclohexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4) ° between them. In the crystal, molecules are linked by weak C - H· · ·Cl hydrogen bonds to generate [001] chains.

Original languageEnglish (US)
Pages (from-to)338-341
Number of pages4
JournalActa Crystallographica Section E: Crystallographic Communications
Volume75
DOIs
StatePublished - Jan 1 2019

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adducts
Crystal structure
chlorides
Atoms
crystal structure
rings
atoms
dihedral angle
Dihedral angle
ligands
Ligands
Tin
oxygen atoms
tin
envelopes
Anions
Conformations
Chlorides
hydrogen bonds
anions

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin- 4-one",
abstract = "In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one-κO)triphenyltin(IV), [Sn(C 6 H 5 ) 3 Cl(C 15 H 19 NOS)], the tin(IV) atom exhibits a trigonal-bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O - Sn - Cl = 175.07 (14) °]. The thiazolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9) ° with respect to the pendant C-phenyl plane and 34.3 (11) ° to the N-cyclohexyl ring (all atoms). The C-phenyl and N-cyclohexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4) ° between them. In the crystal, molecules are linked by weak C - H· · ·Cl hydrogen bonds to generate [001] chains.",
author = "Yennawar, {Hemant P.} and John Tierney and Cannon, {Kevin Charles}",
year = "2019",
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doi = "10.1107/S2056989019001592",
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journal = "Acta Crystallographica Section E: Crystallographic Communications",
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AU - Cannon, Kevin Charles

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N2 - In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one-κO)triphenyltin(IV), [Sn(C 6 H 5 ) 3 Cl(C 15 H 19 NOS)], the tin(IV) atom exhibits a trigonal-bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O - Sn - Cl = 175.07 (14) °]. The thiazolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9) ° with respect to the pendant C-phenyl plane and 34.3 (11) ° to the N-cyclohexyl ring (all atoms). The C-phenyl and N-cyclohexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4) ° between them. In the crystal, molecules are linked by weak C - H· · ·Cl hydrogen bonds to generate [001] chains.

AB - In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one-κO)triphenyltin(IV), [Sn(C 6 H 5 ) 3 Cl(C 15 H 19 NOS)], the tin(IV) atom exhibits a trigonal-bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O - Sn - Cl = 175.07 (14) °]. The thiazolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9) ° with respect to the pendant C-phenyl plane and 34.3 (11) ° to the N-cyclohexyl ring (all atoms). The C-phenyl and N-cyclohexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4) ° between them. In the crystal, molecules are linked by weak C - H· · ·Cl hydrogen bonds to generate [001] chains.

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