Abstract
The crystal structure of [Sm(OPMePh2)4I2]I, 1, was determined by X-ray diffraction and refined anisotropically to a final R value of 0.067 from 3040 reflections with I>3.0σ(I). The space group was P2/a and Z=2. The unit cell dimensions were: a= 17.777(6), b=13.559(2), c=11.656(4) Å, α=γ= 90.0 and β=97.25(3)°. The cation geometry was octahedral with the Sm(III) bonded to two mutually trans I- ions and four OPMePh2 groups. A third non-bonded I- was present elsewhere in the cell. The SmI and SmO distances were 3.077(1) and 2.27(1) Å respectively. Two of the SmOP angles were 172.1(6)° and the other two were 162.0(6)°.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 87-90 |
| Number of pages | 4 |
| Journal | Inorganica Chimica Acta |
| Volume | 118 |
| Issue number | 1 |
| DOIs | |
| State | Published - Aug 1 1986 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
Fingerprint Dive into the research topics of 'Crystal structure of [Sm(OPMePh<sub>2</sub>)<sub>4</sub>I<sub>2</sub>]I. A cationic octahedral complex of samarium(III)'. Together they form a unique fingerprint.
Cite this
Sen, A., Chebolu, V., & Holt, E. M. (1986). Crystal structure of [Sm(OPMePh2)4I2]I. A cationic octahedral complex of samarium(III). Inorganica Chimica Acta, 118(1), 87-90. https://doi.org/10.1016/S0020-1693(00)86414-2