Crystal structure of [Sm(OPMePh2)4I2]I. A cationic octahedral complex of samarium(III)

Ayusman Sen, Venkatasuryanarayana Chebolu, Elizabeth M. Holt

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Abstract

The crystal structure of [Sm(OPMePh2)4I2]I, 1, was determined by X-ray diffraction and refined anisotropically to a final R value of 0.067 from 3040 reflections with I>3.0σ(I). The space group was P2/a and Z=2. The unit cell dimensions were: a= 17.777(6), b=13.559(2), c=11.656(4) Å, α=γ= 90.0 and β=97.25(3)°. The cation geometry was octahedral with the Sm(III) bonded to two mutually trans I- ions and four OPMePh2 groups. A third non-bonded I- was present elsewhere in the cell. The SmI and SmO distances were 3.077(1) and 2.27(1) Å respectively. Two of the SmOP angles were 172.1(6)° and the other two were 162.0(6)°.

Original languageEnglish (US)
Pages (from-to)87-90
Number of pages4
JournalInorganica Chimica Acta
Volume118
Issue number1
DOIs
StatePublished - Aug 1 1986

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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