Crystallization of sol-gel-derived lithium aluminosilicate (LAS) glass ceramic powders

Gye Song Lee, Gary L. Messing, Frans G.A. Delaat

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The gel to glass ceramic conversion of a sol-gel-derived LAS powder was characterized by its gel to glass conversion, nucleation, crystallization and microstructural development. At Tg the gel converts to a glass with a dense skeletal structure and at ∼ 800°C to fully dense, amorphous particles. Crystallization at 860°C to a ß-quartz solid solution is independent of nucleating agents, gel powder particle size and heat treatment. In contrast, crystallization of a melt glass derived from the gel was dependent on nucleation heat treatment, reaching a minimum crystallization temperature of 860°C. As the glass transition temperature and glass structure before crystallization are approximately the same for the gel and melt-derived powders, the lower crystallization temperature of the gel is attributed solely to its surface excess free energy and its effect on nucleation.

Original languageEnglish (US)
Pages (from-to)125-132
Number of pages8
JournalJournal of Non-Crystalline Solids
Volume116
Issue number2-3
DOIs
StatePublished - Feb 2 1990

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

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