Cure characterization of 4-4' diphenylmethane diisocyanate in a saturated steam environment

D. P. Harper, M. P. Wolcott, T. G. Rials

Research output: Contribution to conferencePaper

Abstract

The cure of polymeric 4-4' diphenylmethane diisocyanate (pMDI) in wood composite manufacturing has been the subject of much research. The exact contribution of polyurethane, polyurea, and polyurete formation with pMDI/wood bonding is still debated. This study forgoes the mechanism controversy and studies the cure a whole. Dielectric analysis (DEA) was utilized to monitor the cure of pMDI in controlled heat, steam, and pressure representing those conditions encountered during wood composite manufacturing. A small steam generating press was mounted to a universal testing machine producing saturated steam environments between 110° and 140°C. The degree of conversion calculated from DEA was the basis for further spectroscopic, calorimetric, and lap-shear analysis. DSC and FTIR techniques revealed a large consumption of isocyanate early in cure. However, mechanical strength, as revealed by lap-shear analysis, developed late in cure. Low lap shear strengths and a plateau in conversion rates were detected for 110° and 120°C and may indicate a diffusion-controlled reaction and crystallization effect. A phenomenological approach to kinetics was utilized to model the reaction. Isothermal DEA and dynamic DSC data were fit to a first order autocatalyzed model. ASTM E698 was modified to fit an autocatalyzed model. The modifications were compared to a method of performing a single dynamic temperature ramp to obtain kinetic parameters. Higher activation energies were obtained for DEA than DSC methods. In addition, ASTM methods for DSC produced higher activation energies than single dynamic ramps and compared favorably with data obtained from the previous DSC study. The observed differences in activation energy relate to differing mechanisms in chemical and physical cure.

Original languageEnglish (US)
Number of pages1
StatePublished - Dec 1 1998
EventProceedings of the 1998 32nd International Particleboard/Composite Materials Symposium - Pullman, WA, USA
Duration: Mar 31 1998Apr 2 1998

Other

OtherProceedings of the 1998 32nd International Particleboard/Composite Materials Symposium
CityPullman, WA, USA
Period3/31/984/2/98

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Steam
Wood
Activation energy
Isocyanates
Polyurethanes
Composite materials
Crystallization
Kinetic parameters
Shear strength
Strength of materials
Kinetics
4,4'-diphenylmethane diisocyanate
Testing
polymeric 4,4'-diphenylmethane diisocyanate
Temperature

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Materials Science(all)

Cite this

Harper, D. P., Wolcott, M. P., & Rials, T. G. (1998). Cure characterization of 4-4' diphenylmethane diisocyanate in a saturated steam environment. Paper presented at Proceedings of the 1998 32nd International Particleboard/Composite Materials Symposium, Pullman, WA, USA, .
Harper, D. P. ; Wolcott, M. P. ; Rials, T. G. / Cure characterization of 4-4' diphenylmethane diisocyanate in a saturated steam environment. Paper presented at Proceedings of the 1998 32nd International Particleboard/Composite Materials Symposium, Pullman, WA, USA, .1 p.
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Harper, DP, Wolcott, MP & Rials, TG 1998, 'Cure characterization of 4-4' diphenylmethane diisocyanate in a saturated steam environment', Paper presented at Proceedings of the 1998 32nd International Particleboard/Composite Materials Symposium, Pullman, WA, USA, 3/31/98 - 4/2/98.

Cure characterization of 4-4' diphenylmethane diisocyanate in a saturated steam environment. / Harper, D. P.; Wolcott, M. P.; Rials, T. G.

1998. Paper presented at Proceedings of the 1998 32nd International Particleboard/Composite Materials Symposium, Pullman, WA, USA, .

Research output: Contribution to conferencePaper

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Harper DP, Wolcott MP, Rials TG. Cure characterization of 4-4' diphenylmethane diisocyanate in a saturated steam environment. 1998. Paper presented at Proceedings of the 1998 32nd International Particleboard/Composite Materials Symposium, Pullman, WA, USA, .