Defect structure-electrical property relationship in Mn-doped calcium strontium titanate dielectric ceramics

Lin Zhang, Hua Hao, Shujun Zhang, Michael T. Lanagan, Zhonghua Yao, Qi Xu, Juan Xie, Jing Zhou, Minghe Cao, Hanxing Liu

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Ca 0.6 Sr 0.4 TiO 3 (CST) ceramics with different amounts of Mn dopant (0-2.0 mol%) were prepared by solid-state reaction method. The electric field and temperature stability of energy storage performance was found to be greatly enhanced with moderate doped level of 0.5 mol%. The dielectric loss-frequency spectra revealed the existence and evolution of defect dipoles at elevated temperature, which was confirmed directly by electron paramagnetic resonance (EPR) spectra. The response of defect dipoles was characterized by thermally stimulated depolarization current (TSDC), where the activation energy and the concentration evolution of defect dipoles were calculated, with the highest values observed for 0.5% doped samples. The dissociation of defect dipoles and the movement of free V o ̈ were analyzed by high-temperature impedance spectra analysis, with the activation energy of 1.04-1.60 eV, and 0.5% doped samples also demonstrated the highest E a . The relationship between microscopic defect structure and macroscopic electrical behavior was established in this work.

Original languageEnglish (US)
Pages (from-to)4638-4648
Number of pages11
JournalJournal of the American Ceramic Society
Volume100
Issue number10
DOIs
StatePublished - Oct 1 2017

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Defect structures
Strontium
Calcium
Electric properties
Defects
Activation energy
Depolarization
Dielectric losses
Solid state reactions
Spectrum analysis
Temperature
Energy storage
Paramagnetic resonance
Electric fields
Doping (additives)
strontium titanium oxide

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Zhang, Lin ; Hao, Hua ; Zhang, Shujun ; Lanagan, Michael T. ; Yao, Zhonghua ; Xu, Qi ; Xie, Juan ; Zhou, Jing ; Cao, Minghe ; Liu, Hanxing. / Defect structure-electrical property relationship in Mn-doped calcium strontium titanate dielectric ceramics. In: Journal of the American Ceramic Society. 2017 ; Vol. 100, No. 10. pp. 4638-4648.
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abstract = "Ca 0.6 Sr 0.4 TiO 3 (CST) ceramics with different amounts of Mn dopant (0-2.0 mol{\%}) were prepared by solid-state reaction method. The electric field and temperature stability of energy storage performance was found to be greatly enhanced with moderate doped level of 0.5 mol{\%}. The dielectric loss-frequency spectra revealed the existence and evolution of defect dipoles at elevated temperature, which was confirmed directly by electron paramagnetic resonance (EPR) spectra. The response of defect dipoles was characterized by thermally stimulated depolarization current (TSDC), where the activation energy and the concentration evolution of defect dipoles were calculated, with the highest values observed for 0.5{\%} doped samples. The dissociation of defect dipoles and the movement of free V o ̈ were analyzed by high-temperature impedance spectra analysis, with the activation energy of 1.04-1.60 eV, and 0.5{\%} doped samples also demonstrated the highest E a . The relationship between microscopic defect structure and macroscopic electrical behavior was established in this work.",
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Defect structure-electrical property relationship in Mn-doped calcium strontium titanate dielectric ceramics. / Zhang, Lin; Hao, Hua; Zhang, Shujun; Lanagan, Michael T.; Yao, Zhonghua; Xu, Qi; Xie, Juan; Zhou, Jing; Cao, Minghe; Liu, Hanxing.

In: Journal of the American Ceramic Society, Vol. 100, No. 10, 01.10.2017, p. 4638-4648.

Research output: Contribution to journalArticle

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AU - Zhang, Lin

AU - Hao, Hua

AU - Zhang, Shujun

AU - Lanagan, Michael T.

AU - Yao, Zhonghua

AU - Xu, Qi

AU - Xie, Juan

AU - Zhou, Jing

AU - Cao, Minghe

AU - Liu, Hanxing

PY - 2017/10/1

Y1 - 2017/10/1

N2 - Ca 0.6 Sr 0.4 TiO 3 (CST) ceramics with different amounts of Mn dopant (0-2.0 mol%) were prepared by solid-state reaction method. The electric field and temperature stability of energy storage performance was found to be greatly enhanced with moderate doped level of 0.5 mol%. The dielectric loss-frequency spectra revealed the existence and evolution of defect dipoles at elevated temperature, which was confirmed directly by electron paramagnetic resonance (EPR) spectra. The response of defect dipoles was characterized by thermally stimulated depolarization current (TSDC), where the activation energy and the concentration evolution of defect dipoles were calculated, with the highest values observed for 0.5% doped samples. The dissociation of defect dipoles and the movement of free V o ̈ were analyzed by high-temperature impedance spectra analysis, with the activation energy of 1.04-1.60 eV, and 0.5% doped samples also demonstrated the highest E a . The relationship between microscopic defect structure and macroscopic electrical behavior was established in this work.

AB - Ca 0.6 Sr 0.4 TiO 3 (CST) ceramics with different amounts of Mn dopant (0-2.0 mol%) were prepared by solid-state reaction method. The electric field and temperature stability of energy storage performance was found to be greatly enhanced with moderate doped level of 0.5 mol%. The dielectric loss-frequency spectra revealed the existence and evolution of defect dipoles at elevated temperature, which was confirmed directly by electron paramagnetic resonance (EPR) spectra. The response of defect dipoles was characterized by thermally stimulated depolarization current (TSDC), where the activation energy and the concentration evolution of defect dipoles were calculated, with the highest values observed for 0.5% doped samples. The dissociation of defect dipoles and the movement of free V o ̈ were analyzed by high-temperature impedance spectra analysis, with the activation energy of 1.04-1.60 eV, and 0.5% doped samples also demonstrated the highest E a . The relationship between microscopic defect structure and macroscopic electrical behavior was established in this work.

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