Determining the Fermi level by absorption quenching of monolayer graphene by charge transfer doping

Subash Adhikari, David J. Perello, Chandan Biswas, Arunabha Ghosh, Nguyen Van Luan, Jihoon Park, Fei Yao, Slava V. Rotkin, Young Hee Lee

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

While optical properties of graphene in the visible region are solely defined by the frequency-independent fine structure constant, an onset of absorption has been observed in the infrared region due to Pauli blocking of interband transitions. Here, we report a complete absorption quenching in the infrared region by coating graphene with bis(trifluoromethanesulfonyl)amine (TFSA), an optically transparent p-type chemical dopant. The Fermi level downshift due to TFSA doping results in enhanced transmission in the infrared region proportional to the doping concentration. An absorption quenching onset method, developed in our work, to extract the Fermi level shift in pristine and doped graphene agrees with values extracted from Raman G-band and 2D-band shifts, Hall measurements and the binding energy shift observed in X-ray photo-electron spectroscopy. Performing simple UV-visible transmittance spectroscopy to obtain the absorption quenching onset of graphene also allows detection of environmental and substrate effects via Fermi level shift. Our method opens up the practical implementation of this unique phenomenon of graphene in future optoelectronic devices.

Original languageEnglish (US)
Pages (from-to)18710-18717
Number of pages8
JournalNanoscale
Volume8
Issue number44
DOIs
StatePublished - Nov 28 2016

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Graphite
Fermi level
Graphene
Charge transfer
Quenching
Monolayers
Doping (additives)
Infrared radiation
Amines
Binding energy
Optoelectronic devices
X ray photoelectron spectroscopy
Optical properties
Spectroscopy
Coatings
Substrates

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Adhikari, S., Perello, D. J., Biswas, C., Ghosh, A., Luan, N. V., Park, J., ... Lee, Y. H. (2016). Determining the Fermi level by absorption quenching of monolayer graphene by charge transfer doping. Nanoscale, 8(44), 18710-18717. https://doi.org/10.1039/c6nr05635k
Adhikari, Subash ; Perello, David J. ; Biswas, Chandan ; Ghosh, Arunabha ; Luan, Nguyen Van ; Park, Jihoon ; Yao, Fei ; Rotkin, Slava V. ; Lee, Young Hee. / Determining the Fermi level by absorption quenching of monolayer graphene by charge transfer doping. In: Nanoscale. 2016 ; Vol. 8, No. 44. pp. 18710-18717.
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Adhikari, S, Perello, DJ, Biswas, C, Ghosh, A, Luan, NV, Park, J, Yao, F, Rotkin, SV & Lee, YH 2016, 'Determining the Fermi level by absorption quenching of monolayer graphene by charge transfer doping', Nanoscale, vol. 8, no. 44, pp. 18710-18717. https://doi.org/10.1039/c6nr05635k

Determining the Fermi level by absorption quenching of monolayer graphene by charge transfer doping. / Adhikari, Subash; Perello, David J.; Biswas, Chandan; Ghosh, Arunabha; Luan, Nguyen Van; Park, Jihoon; Yao, Fei; Rotkin, Slava V.; Lee, Young Hee.

In: Nanoscale, Vol. 8, No. 44, 28.11.2016, p. 18710-18717.

Research output: Contribution to journalArticle

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Adhikari S, Perello DJ, Biswas C, Ghosh A, Luan NV, Park J et al. Determining the Fermi level by absorption quenching of monolayer graphene by charge transfer doping. Nanoscale. 2016 Nov 28;8(44):18710-18717. https://doi.org/10.1039/c6nr05635k