Development of electrochemical sensors and their application for characterizing the metal/electrolyte system during localized corrosion

Howard W. Pickering, Konrad G. Weil, Ryan C. Wolfe, Barbara Shaw

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Electrochemical microprobes for in situ monitoring of the electrochemical conditions inside recesses are needed to better understand how localized corrosion and other charge transfer processes occur in confined spaces. The electrode potential distribution can be routinely measured in cavities of > 100 μm opening dimension, but the ability to measure the concentrations of chemical species and their change with time in the presence of potential gradients is only recently becoming possible. Microprobes for pH and chloride ion will be described and results with these sensors will be presented and discussed for creviced iron samples in aqueous electrolytes. Available results reveal, that these species change in concentration and distribution with time both during the induction period before crevice corrosion starts and during propagation of crevice corrosion. Preliminary data show that ionic concentrations peak at locations of highest metal dissolution rate on the crevice wall.

Original languageEnglish (US)
Title of host publicationExtraction and Processing Division Congress 2004
EditorsM.E. Schlesinger
Pages101-116
Number of pages16
Volume2004
StatePublished - Mar 2004
EventExtraction and Processing Division Congress 2004 - Charlotte, NC, United States
Duration: Mar 14 2004Mar 18 2004

Other

OtherExtraction and Processing Division Congress 2004
CountryUnited States
CityCharlotte, NC
Period3/14/043/18/04

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Electrochemical sensors
Electrolytes
Metals
Corrosion
Charge transfer
Chlorides
Dissolution
Iron
Ions
Electrodes
Monitoring
Sensors

All Science Journal Classification (ASJC) codes

  • Filtration and Separation

Cite this

Pickering, H. W., Weil, K. G., Wolfe, R. C., & Shaw, B. (2004). Development of electrochemical sensors and their application for characterizing the metal/electrolyte system during localized corrosion. In M. E. Schlesinger (Ed.), Extraction and Processing Division Congress 2004 (Vol. 2004, pp. 101-116)
Pickering, Howard W. ; Weil, Konrad G. ; Wolfe, Ryan C. ; Shaw, Barbara. / Development of electrochemical sensors and their application for characterizing the metal/electrolyte system during localized corrosion. Extraction and Processing Division Congress 2004. editor / M.E. Schlesinger. Vol. 2004 2004. pp. 101-116
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abstract = "Electrochemical microprobes for in situ monitoring of the electrochemical conditions inside recesses are needed to better understand how localized corrosion and other charge transfer processes occur in confined spaces. The electrode potential distribution can be routinely measured in cavities of > 100 μm opening dimension, but the ability to measure the concentrations of chemical species and their change with time in the presence of potential gradients is only recently becoming possible. Microprobes for pH and chloride ion will be described and results with these sensors will be presented and discussed for creviced iron samples in aqueous electrolytes. Available results reveal, that these species change in concentration and distribution with time both during the induction period before crevice corrosion starts and during propagation of crevice corrosion. Preliminary data show that ionic concentrations peak at locations of highest metal dissolution rate on the crevice wall.",
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Pickering, HW, Weil, KG, Wolfe, RC & Shaw, B 2004, Development of electrochemical sensors and their application for characterizing the metal/electrolyte system during localized corrosion. in ME Schlesinger (ed.), Extraction and Processing Division Congress 2004. vol. 2004, pp. 101-116, Extraction and Processing Division Congress 2004, Charlotte, NC, United States, 3/14/04.

Development of electrochemical sensors and their application for characterizing the metal/electrolyte system during localized corrosion. / Pickering, Howard W.; Weil, Konrad G.; Wolfe, Ryan C.; Shaw, Barbara.

Extraction and Processing Division Congress 2004. ed. / M.E. Schlesinger. Vol. 2004 2004. p. 101-116.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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T1 - Development of electrochemical sensors and their application for characterizing the metal/electrolyte system during localized corrosion

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AU - Wolfe, Ryan C.

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N2 - Electrochemical microprobes for in situ monitoring of the electrochemical conditions inside recesses are needed to better understand how localized corrosion and other charge transfer processes occur in confined spaces. The electrode potential distribution can be routinely measured in cavities of > 100 μm opening dimension, but the ability to measure the concentrations of chemical species and their change with time in the presence of potential gradients is only recently becoming possible. Microprobes for pH and chloride ion will be described and results with these sensors will be presented and discussed for creviced iron samples in aqueous electrolytes. Available results reveal, that these species change in concentration and distribution with time both during the induction period before crevice corrosion starts and during propagation of crevice corrosion. Preliminary data show that ionic concentrations peak at locations of highest metal dissolution rate on the crevice wall.

AB - Electrochemical microprobes for in situ monitoring of the electrochemical conditions inside recesses are needed to better understand how localized corrosion and other charge transfer processes occur in confined spaces. The electrode potential distribution can be routinely measured in cavities of > 100 μm opening dimension, but the ability to measure the concentrations of chemical species and their change with time in the presence of potential gradients is only recently becoming possible. Microprobes for pH and chloride ion will be described and results with these sensors will be presented and discussed for creviced iron samples in aqueous electrolytes. Available results reveal, that these species change in concentration and distribution with time both during the induction period before crevice corrosion starts and during propagation of crevice corrosion. Preliminary data show that ionic concentrations peak at locations of highest metal dissolution rate on the crevice wall.

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M3 - Conference contribution

VL - 2004

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BT - Extraction and Processing Division Congress 2004

A2 - Schlesinger, M.E.

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Pickering HW, Weil KG, Wolfe RC, Shaw B. Development of electrochemical sensors and their application for characterizing the metal/electrolyte system during localized corrosion. In Schlesinger ME, editor, Extraction and Processing Division Congress 2004. Vol. 2004. 2004. p. 101-116