Development of high-power electrodes for a liquid-feed direct methanol fuel cell

C. Lim, C. Y. Wang

Research output: Contribution to journalArticle

94 Scopus citations

Abstract

Based upon Nafion 112 membrane, membrane-electrode assemblies for a liquid-feed direct methanol fuel cell (DMFC) were fabricated by using a novel method of modified Nafion solution and tape-casting, with unsupported Pt-Ru as an anode catalyst and carbon supported 40wt.% Pt as a cathode catalyst. The amounts of catalyst loading were controlled to be 4mg/cm2 in the anode and 1.3mg/cm2 in the cathode. Morphological characteristics of anode and cathode were examined by scanning electron microscopy (SEM). A time-delayed activation effect was found in single cell tests and attributed to time-dependent wetting behavior of Nafion polymers within both catalyst layers. A high compression of the single cell leads to a remarkable decrease in diffusion-limiting current density, caused by hydrophilic broken fibers and cleavage-like defects generated during excessive compression of the cell. A maximum power density of 0.21W/cm2 is achieved in 2M CH3OH solution at 90°C under the operating condition of non-pressurized anode side and non-humidified air pressurized to 15psi.

Original languageEnglish (US)
Pages (from-to)145-150
Number of pages6
JournalJournal of Power Sources
Volume113
Issue number1
DOIs
StatePublished - Jan 1 2003

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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