Quantum yields for C-C bond scission are at least 50 times larger in radical cations of methoxybicumenes (1.+) generated by quenching of the p-tetrachlorobenzoquinone (TCBQ) excited state (a process that results in triplet solvent-separated ion pairs) than in those obtained by the irradiation of [TCBQ ⋯ (1)] charge-transfer complexes (a reaction that yields singlet contact ion pairs).
|Original language||English (US)|
|Number of pages||3|
|Journal||Journal of the Chemical Society, Chemical Communications|
|Publication status||Published - Jan 1 1989|
All Science Journal Classification (ASJC) codes
- Molecular Medicine