Directional self-assembly of ligand-stabilized gold nanoparticles into hollow vesicles through dynamic ligand rearrangement

Robert John Hickey, III, Myungjoo Seo, Qingjie Luo, So Jung Park

Research output: Contribution to journalArticle

11 Scopus citations


Here we report a novel approach to prepare all-nanoparticle vesicles using ligand-stabilized gold particles as a building block. Hydroxyalkyl-terminated gold nanoparticles were spontaneously organized into well-defined hollow vesicle-like assemblies in water without any template. The unusual anisotropic self-assembly was attributed to the ligand rearrangement on nanoparticles, which leads to increased hydroxyl group density at the nanoparticle/water interface. One-dimensional strings were formed instead of vesicles with increasing surface ligand density, which supports the hypothesis. The size and the wall thickness of vesicles were controlled by adjusting the concentration of nanoparticles or by adding extra surfactants. The work presented here highlights the dynamic nature of surface ligands on gold particles and demonstrates that the combination of ligand rearrangement and the hydrophobic effect can be used as a versatile tool for anisotropic self-assembly of nanoparticles.

Original languageEnglish (US)
Pages (from-to)4299-4304
Number of pages6
Issue number14
StatePublished - Apr 14 2015


All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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