Double-negative-index ceramic aerogels for thermal superinsulation

Xiang Xu, Qiangqiang Zhang, Menglong Hao, Yuan Hu, Zhaoyang Lin, Lele Peng, Tao Wang, Xuexin Ren, Chen Wang, Zipeng Zhao, Chengzhang Wan, Huilong Fei, Lei Wang, Jian Zhu, Hongtao Sun, Wenli Chen, Tao Du, Biwei Deng, Gary J. Cheng, Imran ShakirChris Dames, Timothy S. Fisher, Xiang Zhang, Hui Li, Yu Huang, Xiangfeng Duan

Research output: Contribution to journalArticlepeer-review

134 Scopus citations

Abstract

Ceramic aerogels are attractive for thermal insulation but plagued by poor mechanical stability and degradation under thermal shock. In this study, we designed and synthesized hyperbolic architectured ceramic aerogels with nanolayered double-pane walls with a negative Poisson’s ratio (−0.25) and a negative linear thermal expansion coefficient (−1.8 × 10 −6 per °C). Our aerogels display robust mechanical and thermal stability and feature ultralow densities down to ~0.1 milligram per cubic centimeter, superelasticity up to 95%, and near-zero strength loss after sharp thermal shocks (275°C per second) or intense thermal stress at 1400°C, as well as ultralow thermal conductivity in vacuum [~2.4 milliwatts per meter-kelvin (mW/m·K)] and in air (~20 mW/m·K). This robust material system is ideal for thermal superinsulation under extreme conditions, such as those encountered by spacecraft.

Original languageEnglish (US)
Pages (from-to)723-727
Number of pages5
JournalScience
Volume363
Issue number6428
DOIs
StatePublished - Feb 15 2019

All Science Journal Classification (ASJC) codes

  • General

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