Dysprosium-doped cadmium oxide as a gateway material for mid-infrared plasmonics

Edward Sachet, Christopher T. Shelton, Joshua S. Harris, Benjamin E. Gaddy, Douglas L. Irving, Stefano Curtarolo, Brian F. Donovan, Patrick E. Hopkins, Peter A. Sharma, Ana Lima Sharma, Jon Ihlefeld, Stefan Franzen, Jon Paul Maria

Research output: Contribution to journalArticle

134 Scopus citations

Abstract

The interest in plasmonic technologies surrounds many emergent optoelectronic applications, such as plasmon lasers, transistors, sensors and information storage. Although plasmonic materials for ultraviolet-visible and near-infrared wavelengths have been found, the mid-infrared range remains a challenge to address: few known systems can achieve subwavelength optical confinement with low loss in this range. With a combination of experiments and ab initio modelling, here we demonstrate an extreme peak of electron mobility in Dy-doped CdO that is achieved through accurate 'defect equilibrium engineering'. In so doing, we create a tunable plasmon host that satisfies the criteria for mid-infrared spectrum plasmonics, and overcomes the losses seen in conventional plasmonic materials. In particular, extrinsic doping pins the CdO Fermi level above the conduction band minimum and it increases the formation energy of native oxygen vacancies, thus reducing their populations by several orders of magnitude. The substitutional lattice strain induced by Dy doping is sufficiently small, allowing mobility values around 500 cm2 V-1 s-1 for carrier densities above 1020 cm-3. Our work shows that CdO:Dy is a model system for intrinsic and extrinsic manipulation of defects affecting electrical, optical and thermal properties, that oxide conductors are ideal candidates for plasmonic devices and that the defect engineering approach for property optimization is generally applicable to other conducting metal oxides.

Original languageEnglish (US)
Pages (from-to)414-420
Number of pages7
JournalNature Materials
Volume14
Issue number4
DOIs
StatePublished - Apr 2015

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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    Sachet, E., Shelton, C. T., Harris, J. S., Gaddy, B. E., Irving, D. L., Curtarolo, S., Donovan, B. F., Hopkins, P. E., Sharma, P. A., Sharma, A. L., Ihlefeld, J., Franzen, S., & Maria, J. P. (2015). Dysprosium-doped cadmium oxide as a gateway material for mid-infrared plasmonics. Nature Materials, 14(4), 414-420. https://doi.org/10.1038/nmat4203