Effect of adjacent hydrophilic polymer thin films on physical aging and residual stress in thin films of poly(butylnorbornene-ran-hydroxyhexafluoroisopropyl norbornene)

Elizabeth A. Lewis, Christopher M. Stafford, Bryan D. Vogt

Research output: Contribution to journalArticle

Abstract

The properties of thin supported polymer films can be dramatically impacted by the substrate upon which it resides. A simple way to alter the properties of the substrate (chemistry, rigidity, dynamics) is by coating it with an immiscible polymer. Here, we describe how ultrathin (ca. 2 nm) hydrophilic polymer layers of poly(acrylic acid) and poly(styrene sulfonate) (PSS) impact the aging behavior and the residual stress in thin films of poly(butylnorbornene-ran-hydroxyhexafluoroisopropyl norbornene) (BuNB-r-HFANB). The aging rate decreases as the film thickness (h) is decreased, but the extent of this change depends on the adjacent layer. Even for the thickest films (h > 500 nm), there is a decrease in the aging rate at 100 °C when BuNB-r-HFANB is in contact with PSS. In an effort to understand the origins of these differences in the aging behavior, the elastic modulus and residual stress (σR) in the films were determined by wrinkling as a function of aging time. The change in the elastic modulus during aging does not appear to be directly correlated with the densification or expansion of the films, but the aging rates appear to roughly scale as hσR 1/3. These results illustrate that the physical aging of thin polymer films can be altered by adjacent polymers.

Original languageEnglish (US)
Pages (from-to)992-1000
Number of pages9
JournalJournal of Polymer Science, Part B: Polymer Physics
Volume57
Issue number15
DOIs
StatePublished - Jan 1 2019

Fingerprint

Polymer films
residual stress
Residual stresses
Aging of materials
Thin films
polymers
thin films
Polymers
carbopol 940
modulus of elasticity
Elastic moduli
wrinkling
Styrene
2-norbornene
acrylic acid
Substrates
densification
sulfonates
Densification
Thick films

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

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abstract = "The properties of thin supported polymer films can be dramatically impacted by the substrate upon which it resides. A simple way to alter the properties of the substrate (chemistry, rigidity, dynamics) is by coating it with an immiscible polymer. Here, we describe how ultrathin (ca. 2 nm) hydrophilic polymer layers of poly(acrylic acid) and poly(styrene sulfonate) (PSS) impact the aging behavior and the residual stress in thin films of poly(butylnorbornene-ran-hydroxyhexafluoroisopropyl norbornene) (BuNB-r-HFANB). The aging rate decreases as the film thickness (h) is decreased, but the extent of this change depends on the adjacent layer. Even for the thickest films (h > 500 nm), there is a decrease in the aging rate at 100 °C when BuNB-r-HFANB is in contact with PSS. In an effort to understand the origins of these differences in the aging behavior, the elastic modulus and residual stress (σR) in the films were determined by wrinkling as a function of aging time. The change in the elastic modulus during aging does not appear to be directly correlated with the densification or expansion of the films, but the aging rates appear to roughly scale as hσR 1/3. These results illustrate that the physical aging of thin polymer films can be altered by adjacent polymers.",
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AU - Stafford, Christopher M.

AU - Vogt, Bryan D.

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