Effect of diazotization and magnetic assembly on CNT dispersion observed with hardness and modulus measurement of their epoxy composite of low CNT volume fraction

Shreya Trivedi, Melissa Rudolph, Yagmur Atescan, Jingyao Dai, Kayla Cooley, James H. Adair, Suzanne E. Mohney, Namiko Yamamoto

Research output: Contribution to journalArticle

Abstract

Polymer composites with small amount of CNTs (< 5 wt%) have been studied as a light-weight wear-resistant material with low friction, among other applications, but their modulus improvement often plateaus or diminishes with increasing CNT fraction due to agglomeration. Here, polymer nanocomposites were fabricated with randomly oriented or aligned CNTs across their volume (up to 5 mm length) by CNT surface diazotization and by static magnetic field application (400 G for 40 min). With the improved CNT dispersion and thus less agglomeration, the reduced moduli of PNCs stayed improved with addition of up to 1 vol% (or 1.3 wt%) of CNTs. In this work, the PNCs with randomly oriented CNTs exhibited higher stiffness than the PNCs with magnetically aligned and assembled CNTs, indicating again the negative effect of CNT agglomeration on stiffness. In future, other CNT structuring methods with controlled inter-CNT contacts will be conducted to dissociate alignment from local agglomeration of CNTs and thus to simultaneously improve hardness and modulus of PNCs with small CNT addition.

Original languageEnglish (US)
Article number270
JournalJournal of Nanoparticle Research
Volume21
Issue number12
DOIs
StatePublished - Dec 1 2019

Fingerprint

Agglomeration
Epoxy
Volume Fraction
Hardness
Volume fraction
Modulus
hardness
assembly
carbon nanotubes
Composite
composite materials
Composite materials
Stiffness
Polymers
Polymer Composites
agglomeration
Nanocomposites
Friction
Alignment
Magnetic Field

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Atomic and Molecular Physics, and Optics
  • Modeling and Simulation
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Effect of diazotization and magnetic assembly on CNT dispersion observed with hardness and modulus measurement of their epoxy composite of low CNT volume fraction",
abstract = "Polymer composites with small amount of CNTs (< 5 wt{\%}) have been studied as a light-weight wear-resistant material with low friction, among other applications, but their modulus improvement often plateaus or diminishes with increasing CNT fraction due to agglomeration. Here, polymer nanocomposites were fabricated with randomly oriented or aligned CNTs across their volume (up to 5 mm length) by CNT surface diazotization and by static magnetic field application (400 G for 40 min). With the improved CNT dispersion and thus less agglomeration, the reduced moduli of PNCs stayed improved with addition of up to 1 vol{\%} (or 1.3 wt{\%}) of CNTs. In this work, the PNCs with randomly oriented CNTs exhibited higher stiffness than the PNCs with magnetically aligned and assembled CNTs, indicating again the negative effect of CNT agglomeration on stiffness. In future, other CNT structuring methods with controlled inter-CNT contacts will be conducted to dissociate alignment from local agglomeration of CNTs and thus to simultaneously improve hardness and modulus of PNCs with small CNT addition.",
author = "Shreya Trivedi and Melissa Rudolph and Yagmur Atescan and Jingyao Dai and Kayla Cooley and Adair, {James H.} and Mohney, {Suzanne E.} and Namiko Yamamoto",
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Effect of diazotization and magnetic assembly on CNT dispersion observed with hardness and modulus measurement of their epoxy composite of low CNT volume fraction. / Trivedi, Shreya; Rudolph, Melissa; Atescan, Yagmur; Dai, Jingyao; Cooley, Kayla; Adair, James H.; Mohney, Suzanne E.; Yamamoto, Namiko.

In: Journal of Nanoparticle Research, Vol. 21, No. 12, 270, 01.12.2019.

Research output: Contribution to journalArticle

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T1 - Effect of diazotization and magnetic assembly on CNT dispersion observed with hardness and modulus measurement of their epoxy composite of low CNT volume fraction

AU - Trivedi, Shreya

AU - Rudolph, Melissa

AU - Atescan, Yagmur

AU - Dai, Jingyao

AU - Cooley, Kayla

AU - Adair, James H.

AU - Mohney, Suzanne E.

AU - Yamamoto, Namiko

PY - 2019/12/1

Y1 - 2019/12/1

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AB - Polymer composites with small amount of CNTs (< 5 wt%) have been studied as a light-weight wear-resistant material with low friction, among other applications, but their modulus improvement often plateaus or diminishes with increasing CNT fraction due to agglomeration. Here, polymer nanocomposites were fabricated with randomly oriented or aligned CNTs across their volume (up to 5 mm length) by CNT surface diazotization and by static magnetic field application (400 G for 40 min). With the improved CNT dispersion and thus less agglomeration, the reduced moduli of PNCs stayed improved with addition of up to 1 vol% (or 1.3 wt%) of CNTs. In this work, the PNCs with randomly oriented CNTs exhibited higher stiffness than the PNCs with magnetically aligned and assembled CNTs, indicating again the negative effect of CNT agglomeration on stiffness. In future, other CNT structuring methods with controlled inter-CNT contacts will be conducted to dissociate alignment from local agglomeration of CNTs and thus to simultaneously improve hardness and modulus of PNCs with small CNT addition.

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