Effect of glass transition on the concentration dependence of self-diffusion coefficients

J. S. Vrentas, Christine Mary Vrentas

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Abstract

The effect of glass transition on the concentration dependence of self-diffusion coefficients was studied using free-volume theory of diffusion. The variation of the solvent concentration in the polymer-solvent system at a constant temperature was also studied. The theoretical prediction is in agreement with experimental data.

Original languageEnglish (US)
Pages (from-to)1682-1684
Number of pages3
JournalJournal of Applied Polymer Science
Volume89
Issue number6
DOIs
Publication statusPublished - Aug 8 2003

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Materials Chemistry

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