Effect of guest molecule flexibility in access to dendritic interiors

Sivakumar V. Aathimanikandan, Britto S. Sandanaraj, Christopher G. Arges, Christopher J. Bardeen, S. Thayumanavan

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

(Figure Presented) Dendrimers are attractive scaffolds for catalysis, since catalytic sites can be isolated and the catalysts are recoverable and reusable. Herein, we show that conformationally constrained molecules have better access to dendritic cores compared to the more flexible counterparts. The results reported here should have implications in utilizing dendrimers as scaffolds for artificial selectivity in catalysis.

Original languageEnglish (US)
Pages (from-to)2809-2812
Number of pages4
JournalOrganic Letters
Volume7
Issue number14
DOIs
StatePublished - Jul 7 2005

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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