Effect of metals on supercritical water gasification of cellulose and lignin

Fernando L.P. Resende, Phillip E. Savage

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

We gasified cellulose and lignin in supercritical water, using quartz reactors, and quantified the catalytic effect of metals by adding them to these reactors in different forms. We used nickel, iron, copper, zinc, and zirconium wires, ruthenium powder, and Raney nickel slurry. The presence of metals was more likely to increase gas yields to a measurable extent when the catalyst surface area/biomass weight ratio was at least 15 mm2/mg (5.0 wt % biomass loading in our experiments). Nickel and copper typically provided higher gas yields at 5.0 wt % loading, and nickel provided the highest H2 yields at 1.0 wt % loading. SCWG at 500 °C with nickel at 240 mm 2/mg generated 16 mmol/g of H2 from cellulose. CH 4 yields were not strongly influenced by the presence of metals. With nickel wires in the reactor, gas with about 40-50% of the energy content in the original biomass was produced from cellulose and lignin. All of the metals tested except copper produced H2 from water when exposed to SCWG conditions with no biomass. It is important that this background H2 formation be accounted for when interpreting results from SCWG experiments in the presence of metals. Exposure of nickel wires to supercritical water did not reduce their activity for H2 production.

Original languageEnglish (US)
Pages (from-to)2694-2700
Number of pages7
JournalIndustrial and Engineering Chemistry Research
Volume49
Issue number6
DOIs
StatePublished - Mar 17 2010

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Lignin
Nickel
Gasification
Cellulose
Metals
Water
Biomass
Copper
Gases
Wire
Quartz
Ruthenium
Zirconium
Powders
Zinc
Iron
Experiments
Catalysts

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

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abstract = "We gasified cellulose and lignin in supercritical water, using quartz reactors, and quantified the catalytic effect of metals by adding them to these reactors in different forms. We used nickel, iron, copper, zinc, and zirconium wires, ruthenium powder, and Raney nickel slurry. The presence of metals was more likely to increase gas yields to a measurable extent when the catalyst surface area/biomass weight ratio was at least 15 mm2/mg (5.0 wt {\%} biomass loading in our experiments). Nickel and copper typically provided higher gas yields at 5.0 wt {\%} loading, and nickel provided the highest H2 yields at 1.0 wt {\%} loading. SCWG at 500 °C with nickel at 240 mm 2/mg generated 16 mmol/g of H2 from cellulose. CH 4 yields were not strongly influenced by the presence of metals. With nickel wires in the reactor, gas with about 40-50{\%} of the energy content in the original biomass was produced from cellulose and lignin. All of the metals tested except copper produced H2 from water when exposed to SCWG conditions with no biomass. It is important that this background H2 formation be accounted for when interpreting results from SCWG experiments in the presence of metals. Exposure of nickel wires to supercritical water did not reduce their activity for H2 production.",
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Effect of metals on supercritical water gasification of cellulose and lignin. / Resende, Fernando L.P.; Savage, Phillip E.

In: Industrial and Engineering Chemistry Research, Vol. 49, No. 6, 17.03.2010, p. 2694-2700.

Research output: Contribution to journalArticle

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