Effect of nanoscale phase separation on the fracture behavior of glasses: Toward tough, yet transparent glasses

Longwen Tang, N. M. Anoop Krishnan, Jonathan Berjikian, Jared Rivera, Morten M. Smedskjaer, John C. Mauro, Wei Zhou, Mathieu Bauchy

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Although oxide glasses have many unique properties, their range of applications remains limited by their brittleness. By mimicking the microstructure of composite materials, the presence of controlled nanoscale phase separation in glass could overcome this limitation. However, the nature of the toughening mechanism induced by such nanostructuring remains poorly understood. Here, based on peridynamic simulations, we investigate the effect of nanoscale phase separation on the crack propagation mechanism. We show that phase separation can significantly increase glass's toughness (with up to a 90% increase in the fracture energy for the range of conditions investigated herein). The extent of toughening is found to arise from a balance between the overall cohesion of the phase-separated glass and the propensity for crack deflection. This suggests that controlled nanoscale phase separation is a promising route toward the development of tough, yet optically transparent glasses.

Original languageEnglish (US)
Article number113602
JournalPhysical Review Materials
Volume2
Issue number11
DOIs
StatePublished - Nov 8 2018

Fingerprint

Phase separation
Glass
glass
Toughening
brittleness
Fracture energy
cohesion
crack propagation
toughness
Brittleness
Oxides
Toughness
deflection
Crack propagation
cracks
routes
Cracks
microstructure
Microstructure
composite materials

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Physics and Astronomy (miscellaneous)

Cite this

Tang, Longwen ; Anoop Krishnan, N. M. ; Berjikian, Jonathan ; Rivera, Jared ; Smedskjaer, Morten M. ; Mauro, John C. ; Zhou, Wei ; Bauchy, Mathieu. / Effect of nanoscale phase separation on the fracture behavior of glasses : Toward tough, yet transparent glasses. In: Physical Review Materials. 2018 ; Vol. 2, No. 11.
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abstract = "Although oxide glasses have many unique properties, their range of applications remains limited by their brittleness. By mimicking the microstructure of composite materials, the presence of controlled nanoscale phase separation in glass could overcome this limitation. However, the nature of the toughening mechanism induced by such nanostructuring remains poorly understood. Here, based on peridynamic simulations, we investigate the effect of nanoscale phase separation on the crack propagation mechanism. We show that phase separation can significantly increase glass's toughness (with up to a 90{\%} increase in the fracture energy for the range of conditions investigated herein). The extent of toughening is found to arise from a balance between the overall cohesion of the phase-separated glass and the propensity for crack deflection. This suggests that controlled nanoscale phase separation is a promising route toward the development of tough, yet optically transparent glasses.",
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Effect of nanoscale phase separation on the fracture behavior of glasses : Toward tough, yet transparent glasses. / Tang, Longwen; Anoop Krishnan, N. M.; Berjikian, Jonathan; Rivera, Jared; Smedskjaer, Morten M.; Mauro, John C.; Zhou, Wei; Bauchy, Mathieu.

In: Physical Review Materials, Vol. 2, No. 11, 113602, 08.11.2018.

Research output: Contribution to journalArticle

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AU - Tang, Longwen

AU - Anoop Krishnan, N. M.

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AU - Rivera, Jared

AU - Smedskjaer, Morten M.

AU - Mauro, John C.

AU - Zhou, Wei

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