EFFECT OF SIDECHAIN LENGTH AND CROSSLINKING ON IONIC CONDUCTIVITY IN POLYPHOSPHAZENE SOLID ELECTROLYTES.

J. S. Tonge, P. M. Blonsky, D. F. Shriver, Harry R. Allcock, P. E. Austin, T. X. Neenan, J. T. Sisko

Research output: Contribution to journalConference article

9 Citations (Scopus)

Abstract

We report the synthesis and characterization of new linear and crosslinked phosphazene polymers which are suitable solid electrolyte host materials. The effect on the physical properties of variations of the side chain length in a series of poly(alkoxy)phosphazene, left brace NP left bracket O)C//2H//4O) xCH//3 right bracket //2 right brace //n (x equals 1,2,7,12 and 17), salt complexes was investigated. A polymer salt complex with a conductivity of 5. 3 multiplied by 10** minus **5 Scm** minus **1 was obtained at 30 degree C when x equals 7 with LiSO//3CF//3. For x equals 2 crosslinks were introduced by glycol bridges. Polymer-salt complexes of the crosslinked material have vastly improved dimensional stability and conductivities comparable to their linear analogs.

Original languageEnglish (US)
Pages (from-to)533-544
Number of pages12
JournalProceedings - The Electrochemical Society
Volume87-1
StatePublished - Dec 1 1987

Fingerprint

Solid electrolytes
Ionic conductivity
Crosslinking
Salts
Polymers
Dimensional stability
Glycols
Chain length
Physical properties

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Tonge, J. S., Blonsky, P. M., Shriver, D. F., Allcock, H. R., Austin, P. E., Neenan, T. X., & Sisko, J. T. (1987). EFFECT OF SIDECHAIN LENGTH AND CROSSLINKING ON IONIC CONDUCTIVITY IN POLYPHOSPHAZENE SOLID ELECTROLYTES. Proceedings - The Electrochemical Society, 87-1, 533-544.
Tonge, J. S. ; Blonsky, P. M. ; Shriver, D. F. ; Allcock, Harry R. ; Austin, P. E. ; Neenan, T. X. ; Sisko, J. T. / EFFECT OF SIDECHAIN LENGTH AND CROSSLINKING ON IONIC CONDUCTIVITY IN POLYPHOSPHAZENE SOLID ELECTROLYTES. In: Proceedings - The Electrochemical Society. 1987 ; Vol. 87-1. pp. 533-544.
@article{73d260ffe51440899ea3baa253cf7267,
title = "EFFECT OF SIDECHAIN LENGTH AND CROSSLINKING ON IONIC CONDUCTIVITY IN POLYPHOSPHAZENE SOLID ELECTROLYTES.",
abstract = "We report the synthesis and characterization of new linear and crosslinked phosphazene polymers which are suitable solid electrolyte host materials. The effect on the physical properties of variations of the side chain length in a series of poly(alkoxy)phosphazene, left brace NP left bracket O)C//2H//4O) xCH//3 right bracket //2 right brace //n (x equals 1,2,7,12 and 17), salt complexes was investigated. A polymer salt complex with a conductivity of 5. 3 multiplied by 10** minus **5 Scm** minus **1 was obtained at 30 degree C when x equals 7 with LiSO//3CF//3. For x equals 2 crosslinks were introduced by glycol bridges. Polymer-salt complexes of the crosslinked material have vastly improved dimensional stability and conductivities comparable to their linear analogs.",
author = "Tonge, {J. S.} and Blonsky, {P. M.} and Shriver, {D. F.} and Allcock, {Harry R.} and Austin, {P. E.} and Neenan, {T. X.} and Sisko, {J. T.}",
year = "1987",
month = "12",
day = "1",
language = "English (US)",
volume = "87-1",
pages = "533--544",
journal = "Proceedings - The Electrochemical Society",
issn = "0161-6374",

}

Tonge, JS, Blonsky, PM, Shriver, DF, Allcock, HR, Austin, PE, Neenan, TX & Sisko, JT 1987, 'EFFECT OF SIDECHAIN LENGTH AND CROSSLINKING ON IONIC CONDUCTIVITY IN POLYPHOSPHAZENE SOLID ELECTROLYTES.', Proceedings - The Electrochemical Society, vol. 87-1, pp. 533-544.

EFFECT OF SIDECHAIN LENGTH AND CROSSLINKING ON IONIC CONDUCTIVITY IN POLYPHOSPHAZENE SOLID ELECTROLYTES. / Tonge, J. S.; Blonsky, P. M.; Shriver, D. F.; Allcock, Harry R.; Austin, P. E.; Neenan, T. X.; Sisko, J. T.

In: Proceedings - The Electrochemical Society, Vol. 87-1, 01.12.1987, p. 533-544.

Research output: Contribution to journalConference article

TY - JOUR

T1 - EFFECT OF SIDECHAIN LENGTH AND CROSSLINKING ON IONIC CONDUCTIVITY IN POLYPHOSPHAZENE SOLID ELECTROLYTES.

AU - Tonge, J. S.

AU - Blonsky, P. M.

AU - Shriver, D. F.

AU - Allcock, Harry R.

AU - Austin, P. E.

AU - Neenan, T. X.

AU - Sisko, J. T.

PY - 1987/12/1

Y1 - 1987/12/1

N2 - We report the synthesis and characterization of new linear and crosslinked phosphazene polymers which are suitable solid electrolyte host materials. The effect on the physical properties of variations of the side chain length in a series of poly(alkoxy)phosphazene, left brace NP left bracket O)C//2H//4O) xCH//3 right bracket //2 right brace //n (x equals 1,2,7,12 and 17), salt complexes was investigated. A polymer salt complex with a conductivity of 5. 3 multiplied by 10** minus **5 Scm** minus **1 was obtained at 30 degree C when x equals 7 with LiSO//3CF//3. For x equals 2 crosslinks were introduced by glycol bridges. Polymer-salt complexes of the crosslinked material have vastly improved dimensional stability and conductivities comparable to their linear analogs.

AB - We report the synthesis and characterization of new linear and crosslinked phosphazene polymers which are suitable solid electrolyte host materials. The effect on the physical properties of variations of the side chain length in a series of poly(alkoxy)phosphazene, left brace NP left bracket O)C//2H//4O) xCH//3 right bracket //2 right brace //n (x equals 1,2,7,12 and 17), salt complexes was investigated. A polymer salt complex with a conductivity of 5. 3 multiplied by 10** minus **5 Scm** minus **1 was obtained at 30 degree C when x equals 7 with LiSO//3CF//3. For x equals 2 crosslinks were introduced by glycol bridges. Polymer-salt complexes of the crosslinked material have vastly improved dimensional stability and conductivities comparable to their linear analogs.

UR - http://www.scopus.com/inward/record.url?scp=0023541345&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0023541345&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0023541345

VL - 87-1

SP - 533

EP - 544

JO - Proceedings - The Electrochemical Society

JF - Proceedings - The Electrochemical Society

SN - 0161-6374

ER -