Effect of solvent size on solvent self-diffusion in polymer-solvent systems

J. S. Vrentas, C. M. Vrentas, N. Faridi

Research output: Contribution to journalArticle

65 Scopus citations

Abstract

The free-volume theory for solvent self-diffusion coefficients in polymer-solvent systems is modified to include a more general analysis of the effects of solvent size. The predictions of the theory are compared with self-diffusion data for a diverse set of solvents and four polymers, polystyrene, poly-(vinyl acetate), poly(methyl methacrylate), and poly(p-methylstyrene). The new prediction of size effects is based on the consideration of the asymmetry of solvent molecules.

Original languageEnglish (US)
Pages (from-to)3272-3276
Number of pages5
JournalMacromolecules
Volume29
Issue number9
DOIs
StatePublished - Apr 22 1996

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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