Effect of the polymer glass transition on the chromatographic retention volumes

J. S. Vrentas, C. M. Vrentas

Research output: Contribution to journalArticle

Abstract

Theoretical developments are presented that explain four experimental observations concerning the temperature dependence of Chromatographic specific retention volumes. A theoretical framework is proposed for a method that can be used to determine the glass-transition temperature of the pure polymer and for a method of characterizing the concentration dependence of the glass-transition temperature of a polymer-solvent system.

Original languageEnglish (US)
Pages (from-to)793-796
Number of pages4
JournalJournal of Applied Polymer Science
Volume97
Issue number3
DOIs
StatePublished - Aug 5 2005

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Materials Chemistry

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