Effect of type of polymers loaded in mesoporous carbon dioxide "molecular basket" adsorbent on carbon dioxide separation from gas mixtures

Xiaochun Xu, Bronwyn Graeffe, Chunshan Song

Research output: Contribution to journalConference article

Abstract

Separation of CO2 from various gaseous streams is becoming increasingly important in the field of energy production and sustainable use of fossil energy. A new kind of CO2 "molecular basket", which shows high CO2 capacity and superior CO2 selectivity, was developed. The effect of different types of PEI on the adsorption separation performance of the CO2 "molecular basket" adsorbents was presented. Highly effective CO2 "molecular basket" adsorbent could be prepared by using mesoporous molecular sieve MCM-41 and polyethylenimine with a linear structure. The adsorbent with linear PEI showed a higher CO2 adsorption capacity and a faster CO2 adsorption/desorption rate, than those for the "molecular basket" adsorbent with branched PEI. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).

Original languageEnglish (US)
JournalACS National Meeting Book of Abstracts
Volume227
Issue number1
StatePublished - Jan 1 2004
Event227th ACS National Meeting Abstracts of Papers - Anaheim, CA., United States
Duration: Mar 28 2004Apr 1 2004

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Carbon Dioxide
Gas mixtures
Adsorbents
Polyetherimides
Carbon dioxide
Polymers
Adsorption
Polyethyleneimine
Molecular sieves
Multicarrier modulation
Desorption

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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abstract = "Separation of CO2 from various gaseous streams is becoming increasingly important in the field of energy production and sustainable use of fossil energy. A new kind of CO2 {"}molecular basket{"}, which shows high CO2 capacity and superior CO2 selectivity, was developed. The effect of different types of PEI on the adsorption separation performance of the CO2 {"}molecular basket{"} adsorbents was presented. Highly effective CO2 {"}molecular basket{"} adsorbent could be prepared by using mesoporous molecular sieve MCM-41 and polyethylenimine with a linear structure. The adsorbent with linear PEI showed a higher CO2 adsorption capacity and a faster CO2 adsorption/desorption rate, than those for the {"}molecular basket{"} adsorbent with branched PEI. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).",
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Effect of type of polymers loaded in mesoporous carbon dioxide "molecular basket" adsorbent on carbon dioxide separation from gas mixtures. / Xu, Xiaochun; Graeffe, Bronwyn; Song, Chunshan.

In: ACS National Meeting Book of Abstracts, Vol. 227, No. 1, 01.01.2004.

Research output: Contribution to journalConference article

TY - JOUR

T1 - Effect of type of polymers loaded in mesoporous carbon dioxide "molecular basket" adsorbent on carbon dioxide separation from gas mixtures

AU - Xu, Xiaochun

AU - Graeffe, Bronwyn

AU - Song, Chunshan

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N2 - Separation of CO2 from various gaseous streams is becoming increasingly important in the field of energy production and sustainable use of fossil energy. A new kind of CO2 "molecular basket", which shows high CO2 capacity and superior CO2 selectivity, was developed. The effect of different types of PEI on the adsorption separation performance of the CO2 "molecular basket" adsorbents was presented. Highly effective CO2 "molecular basket" adsorbent could be prepared by using mesoporous molecular sieve MCM-41 and polyethylenimine with a linear structure. The adsorbent with linear PEI showed a higher CO2 adsorption capacity and a faster CO2 adsorption/desorption rate, than those for the "molecular basket" adsorbent with branched PEI. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).

AB - Separation of CO2 from various gaseous streams is becoming increasingly important in the field of energy production and sustainable use of fossil energy. A new kind of CO2 "molecular basket", which shows high CO2 capacity and superior CO2 selectivity, was developed. The effect of different types of PEI on the adsorption separation performance of the CO2 "molecular basket" adsorbents was presented. Highly effective CO2 "molecular basket" adsorbent could be prepared by using mesoporous molecular sieve MCM-41 and polyethylenimine with a linear structure. The adsorbent with linear PEI showed a higher CO2 adsorption capacity and a faster CO2 adsorption/desorption rate, than those for the "molecular basket" adsorbent with branched PEI. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).

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