Electric-field-induced alignment of block copolymer/nanoparticle blends

Clemens Liedel, Kerstin A. Schindler, Mariela J. Pavan, Christian Lewin, Christian Pester, Markus Ruppel, Volker S. Urban, Roy Shenhar, Alexander Böker

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

External electric fields readily align birefringent block-copolymer mesophases. In this study the effect of gold nanoparticles on the electric-field-induced alignment of a lamellae-forming polystyrene-block-poly(2- vinylpyridine) copolymer is assessed. Nanoparticles are homogeneously dispersed in the styrenic phase and promote the quantitative alignment of lamellar domains by substantially lowering the critical field strength above which alignment proceeds. The results suggest that the electric-field-assisted alignment of nanostructured block copolymer/nanoparticle composites may offer a simple way to greatly mitigate structural and orientational defects of such films under benign experimental conditions. Similar to neat block copolymers, nanocomposites composed of polystyrene-block-poly(2-vinyl pyridine) and gold nanoparticles can be aligned in electric fields, which leads to a striped and aligned structure of nanoparticles after removal of the polymer. The onset of domain alignment in the presence of nanosized gold particles occurs at a substantially lower field than for corresponding films in the absence of particles, and decreases with increasing nanoparticle concentration.

Original languageEnglish (US)
Pages (from-to)3276-3281
Number of pages6
JournalSmall
Volume9
Issue number19
DOIs
StatePublished - Oct 11 2013

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Nanoparticles
Block copolymers
Electric fields
Gold
Polystyrenes
Nanocomposites
Pyridine
Polymers
Copolymers
Defects
Composite materials

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)
  • Engineering (miscellaneous)

Cite this

Liedel, C., Schindler, K. A., Pavan, M. J., Lewin, C., Pester, C., Ruppel, M., ... Böker, A. (2013). Electric-field-induced alignment of block copolymer/nanoparticle blends. Small, 9(19), 3276-3281. https://doi.org/10.1002/smll.201202380
Liedel, Clemens ; Schindler, Kerstin A. ; Pavan, Mariela J. ; Lewin, Christian ; Pester, Christian ; Ruppel, Markus ; Urban, Volker S. ; Shenhar, Roy ; Böker, Alexander. / Electric-field-induced alignment of block copolymer/nanoparticle blends. In: Small. 2013 ; Vol. 9, No. 19. pp. 3276-3281.
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Liedel, C, Schindler, KA, Pavan, MJ, Lewin, C, Pester, C, Ruppel, M, Urban, VS, Shenhar, R & Böker, A 2013, 'Electric-field-induced alignment of block copolymer/nanoparticle blends', Small, vol. 9, no. 19, pp. 3276-3281. https://doi.org/10.1002/smll.201202380

Electric-field-induced alignment of block copolymer/nanoparticle blends. / Liedel, Clemens; Schindler, Kerstin A.; Pavan, Mariela J.; Lewin, Christian; Pester, Christian; Ruppel, Markus; Urban, Volker S.; Shenhar, Roy; Böker, Alexander.

In: Small, Vol. 9, No. 19, 11.10.2013, p. 3276-3281.

Research output: Contribution to journalArticle

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AU - Liedel, Clemens

AU - Schindler, Kerstin A.

AU - Pavan, Mariela J.

AU - Lewin, Christian

AU - Pester, Christian

AU - Ruppel, Markus

AU - Urban, Volker S.

AU - Shenhar, Roy

AU - Böker, Alexander

PY - 2013/10/11

Y1 - 2013/10/11

N2 - External electric fields readily align birefringent block-copolymer mesophases. In this study the effect of gold nanoparticles on the electric-field-induced alignment of a lamellae-forming polystyrene-block-poly(2- vinylpyridine) copolymer is assessed. Nanoparticles are homogeneously dispersed in the styrenic phase and promote the quantitative alignment of lamellar domains by substantially lowering the critical field strength above which alignment proceeds. The results suggest that the electric-field-assisted alignment of nanostructured block copolymer/nanoparticle composites may offer a simple way to greatly mitigate structural and orientational defects of such films under benign experimental conditions. Similar to neat block copolymers, nanocomposites composed of polystyrene-block-poly(2-vinyl pyridine) and gold nanoparticles can be aligned in electric fields, which leads to a striped and aligned structure of nanoparticles after removal of the polymer. The onset of domain alignment in the presence of nanosized gold particles occurs at a substantially lower field than for corresponding films in the absence of particles, and decreases with increasing nanoparticle concentration.

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Liedel C, Schindler KA, Pavan MJ, Lewin C, Pester C, Ruppel M et al. Electric-field-induced alignment of block copolymer/nanoparticle blends. Small. 2013 Oct 11;9(19):3276-3281. https://doi.org/10.1002/smll.201202380