Electrical breakdown and ultrahigh electrical energy density in poly(vinylidene fluoride-hexafluoropropylene) copolymer

Xin Zhou; Xuanhe Zhao; Zhigang Suo; Chen Zou; James Runt; Sheng Liu; Shihai Zhang; Q. M. Zhang

doi:10.1063/1.3123001

Electrical breakdown and ultrahigh electrical energy density in poly(vinylidene fluoride-hexafluoropropylene) copolymer

Xin Zhou, Xuanhe Zhao, Zhigang Suo, Chen Zou, James Runt, Sheng Liu, Shihai Zhang, Q. M. Zhang

Research output: Contribution to journal › Article › peer-review

196 Scopus citations

Abstract

This paper investigates the electrical breakdown of a polar fluoropolymer, poly(vinylidene fluoride-hexafluoropropylene) which exhibits an exceptionally high discharged electrical energy density (>25 J/ cm3). It is shown that above room temperature, the breakdown strength decreases with temperature. It is further shown that such a temperature dependence of breakdown strength is consistent with the electromechanical breakdown model by taking into consideration of the plastic deformation of semicrystalline polymers.

Original language	English (US)
Article number	162901
Journal	Applied Physics Letters
Volume	94
Issue number	16
DOIs	https://doi.org/10.1063/1.3123001
State	Published - 2009

All Science Journal Classification (ASJC) codes

Physics and Astronomy (miscellaneous)

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10.1063/1.3123001

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title = "Electrical breakdown and ultrahigh electrical energy density in poly(vinylidene fluoride-hexafluoropropylene) copolymer",

abstract = "This paper investigates the electrical breakdown of a polar fluoropolymer, poly(vinylidene fluoride-hexafluoropropylene) which exhibits an exceptionally high discharged electrical energy density (>25 J/ cm3). It is shown that above room temperature, the breakdown strength decreases with temperature. It is further shown that such a temperature dependence of breakdown strength is consistent with the electromechanical breakdown model by taking into consideration of the plastic deformation of semicrystalline polymers.",

author = "Xin Zhou and Xuanhe Zhao and Zhigang Suo and Chen Zou and James Runt and Sheng Liu and Shihai Zhang and Zhang, {Q. M.}",

note = "Funding Information: The authors from Penn State acknowledge financial support from ONR (Grant No. N00014-05-1-0455) and MURI (Grant No. N00014-05-1-0541). Z.G.S. and X.H.Z. from Harvard University acknowledge financial support from NSF through Project No. CMMI-0800161 on large deformation and instability in soft active materials. ",

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AU - Zhou, Xin

AU - Zhao, Xuanhe

AU - Suo, Zhigang

AU - Zou, Chen

AU - Runt, James

AU - Liu, Sheng

AU - Zhang, Shihai

AU - Zhang, Q. M.

N1 - Funding Information: The authors from Penn State acknowledge financial support from ONR (Grant No. N00014-05-1-0455) and MURI (Grant No. N00014-05-1-0541). Z.G.S. and X.H.Z. from Harvard University acknowledge financial support from NSF through Project No. CMMI-0800161 on large deformation and instability in soft active materials.

PY - 2009

Y1 - 2009

N2 - This paper investigates the electrical breakdown of a polar fluoropolymer, poly(vinylidene fluoride-hexafluoropropylene) which exhibits an exceptionally high discharged electrical energy density (>25 J/ cm3). It is shown that above room temperature, the breakdown strength decreases with temperature. It is further shown that such a temperature dependence of breakdown strength is consistent with the electromechanical breakdown model by taking into consideration of the plastic deformation of semicrystalline polymers.

AB - This paper investigates the electrical breakdown of a polar fluoropolymer, poly(vinylidene fluoride-hexafluoropropylene) which exhibits an exceptionally high discharged electrical energy density (>25 J/ cm3). It is shown that above room temperature, the breakdown strength decreases with temperature. It is further shown that such a temperature dependence of breakdown strength is consistent with the electromechanical breakdown model by taking into consideration of the plastic deformation of semicrystalline polymers.

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Electrical breakdown and ultrahigh electrical energy density in poly(vinylidene fluoride-hexafluoropropylene) copolymer

Abstract

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