TY - JOUR
T1 - Electrical properties of 0.94Bi0.5Na0.5TiO3–0.06Ba(Zr0.055Ti0.945)O3 lead-free ceramics with high thermal stability
AU - Wang, Jun Jun
AU - Guo, Fei Fei
AU - Yang, Bin
AU - Zhang, Shan Tao
AU - Zheng, Li Mei
AU - Wu, Feng Min
AU - Cao, Wen Wu
N1 - Funding Information:
Acknowledgements This work was supported by the National Key Basic Research Program of China (No. 2013CB632900), the National Science Foundation of China (Nos. 51572055, 51572056, 51402075).
Publisher Copyright:
© 2017, Springer Science+Business Media, LLC.
PY - 2018/2/1
Y1 - 2018/2/1
N2 - Here we report the 0.94(Bi0.5Na0.5)TiO3–0.06Ba(Zr0.055Ti0.945)O3 (0.94BNT–0.06BZT) lead-free ceramics was synthesized by two-step solid state reaction route. The structural, dielectric, ferroelectric, piezoelectric and electromechanical properties of the ceramics were studied, and showed excellent electric properties (Ps = 39.9 μC/cm2, Pr = 33.7 μC/cm2, Ec = 2.79 kV/mm, S = 0.20%, d33 = 174 pC/N, kp = 0.33). The depolarization temperature (Td) of the ceramics is about 65 °C, which is determined from the first hump of relative dielectric constant. The electromechanical factor kp disappears at 65 °C, is consistent with the depolarization temperature (Td) and the ferroelectric-antiferroelectric phase transition temperature (Tfe−afe) determined from the temperature-dependent P–E and bipolar S–E curves. These results indicate the 0.94BNT–0.06BZT ceramics has a good thermal stability in range of − 60–60 °C, and meets the actual demand.
AB - Here we report the 0.94(Bi0.5Na0.5)TiO3–0.06Ba(Zr0.055Ti0.945)O3 (0.94BNT–0.06BZT) lead-free ceramics was synthesized by two-step solid state reaction route. The structural, dielectric, ferroelectric, piezoelectric and electromechanical properties of the ceramics were studied, and showed excellent electric properties (Ps = 39.9 μC/cm2, Pr = 33.7 μC/cm2, Ec = 2.79 kV/mm, S = 0.20%, d33 = 174 pC/N, kp = 0.33). The depolarization temperature (Td) of the ceramics is about 65 °C, which is determined from the first hump of relative dielectric constant. The electromechanical factor kp disappears at 65 °C, is consistent with the depolarization temperature (Td) and the ferroelectric-antiferroelectric phase transition temperature (Tfe−afe) determined from the temperature-dependent P–E and bipolar S–E curves. These results indicate the 0.94BNT–0.06BZT ceramics has a good thermal stability in range of − 60–60 °C, and meets the actual demand.
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U2 - 10.1007/s10854-017-8154-1
DO - 10.1007/s10854-017-8154-1
M3 - Article
AN - SCOPUS:85032671002
VL - 29
SP - 2357
EP - 2362
JO - Journal of Materials Science: Materials in Electronics
JF - Journal of Materials Science: Materials in Electronics
SN - 0957-4522
IS - 3
ER -