Electrochemical Control of Copper Intercalation into Nanoscale Bi2Se3

Jinsong Zhang, Jie Sun, Yanbin Li, Feifei Shi, Yi Cui

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Intercalation of exotic atoms or molecules into the layered materials remains an extensively investigated subject in current physics and chemistry. However, traditionally melt-growth and chemical interaction strategies are either limited by insufficiency of intercalant concentrations or destitute of accurate controllability. Here, we have developed a general electrochemical intercalation method to efficaciously regulate the concentration of zerovalent copper atoms into layered Bi2Se3, followed by comprehensive experimental characterization and analyses. Up to 57% copper atoms (Cu6.7Bi2Se3) can be intercalated with no disruption to the host lattice. Meanwhile the unconventional resistance dip accompanied by a hysteresis loop below 40 K, as well as the emergence of new Raman peak in CuxBi2Se3, is a distinct manifestation of the interplay between intercalated Cu atoms with Bi2Se3 host. Our work demonstrates a new methodology to study fundamentally new and unexpected physical behaviors in intercalated metastable materials.

Original languageEnglish (US)
Pages (from-to)1741-1747
Number of pages7
JournalNano letters
Volume17
Issue number3
DOIs
StatePublished - Mar 8 2017

Fingerprint

Intercalation
intercalation
Copper
copper
Atoms
atoms
controllability
Hysteresis loops
Controllability
Physics
hysteresis
methodology
chemistry
physics
Molecules
molecules
interactions

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

Cite this

Zhang, Jinsong ; Sun, Jie ; Li, Yanbin ; Shi, Feifei ; Cui, Yi. / Electrochemical Control of Copper Intercalation into Nanoscale Bi2Se3. In: Nano letters. 2017 ; Vol. 17, No. 3. pp. 1741-1747.
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Electrochemical Control of Copper Intercalation into Nanoscale Bi2Se3. / Zhang, Jinsong; Sun, Jie; Li, Yanbin; Shi, Feifei; Cui, Yi.

In: Nano letters, Vol. 17, No. 3, 08.03.2017, p. 1741-1747.

Research output: Contribution to journalArticle

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T1 - Electrochemical Control of Copper Intercalation into Nanoscale Bi2Se3

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AB - Intercalation of exotic atoms or molecules into the layered materials remains an extensively investigated subject in current physics and chemistry. However, traditionally melt-growth and chemical interaction strategies are either limited by insufficiency of intercalant concentrations or destitute of accurate controllability. Here, we have developed a general electrochemical intercalation method to efficaciously regulate the concentration of zerovalent copper atoms into layered Bi2Se3, followed by comprehensive experimental characterization and analyses. Up to 57% copper atoms (Cu6.7Bi2Se3) can be intercalated with no disruption to the host lattice. Meanwhile the unconventional resistance dip accompanied by a hysteresis loop below 40 K, as well as the emergence of new Raman peak in CuxBi2Se3, is a distinct manifestation of the interplay between intercalated Cu atoms with Bi2Se3 host. Our work demonstrates a new methodology to study fundamentally new and unexpected physical behaviors in intercalated metastable materials.

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