Electronic structure models of oxygen adsorption at the solvated, electrified Pt(111) interface

Kuan Yu Yeh, Sally A. Wasileski, Michael John Janik

Research output: Contribution to journalArticle

29 Scopus citations

Abstract

The adsorption of molecular oxygen is the first step in the oxygen reduction reaction. Influences of interfacial water structure and electrode potential on oxygen adsorption to the Pt(111) surface were evaluated using density functional theory. Two approaches were used to model the electrification of the interface, an applied homogeneous electric field and the double-reference method of Filhol, Taylor, and Neurock. The free energy change for molecular oxygen replacement of water at the surface shows qualitatively different trends between the two models. The inclusion of solvation effects and direct control of the electrode potential offered by the double-reference method lead to the conclusion that O2 replacement of water is favorable at all potentials studied, and O2 binding becomes more favorable with increasing potential. This trend is contrary to that observed using an external electric field model to represent the electrochemical double layer, and arises due to the compounded effect of potential on water-surface, oxygen-surface, and water-molecular oxygen interactions. These results indicate that oxygen replacement of adsorbed water does not limit the overall oxygen reduction reaction rate at a proton-exchange membrane fuel cell cathode. The impacts of aspects of model construction (number of water layers, water density) and variation of electrode potential on the O2-Pt(111) interaction are described.

Original languageEnglish (US)
Pages (from-to)10108-10117
Number of pages10
JournalPhysical Chemistry Chemical Physics
Volume11
Issue number43
DOIs
StatePublished - Nov 16 2009

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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