Electrostrictive Coefficient of a Rocksalt-Type Oxide MgO

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Abstract

The electric-displacement-related electrostrictive coefficient Qh of a rocksalt-type oxide, MgO, has been determined as 0.16 m4C-2 by measuring the hydrostatic pressure dependence of the reciprocal permittivity(Qh=(l/2)[∂(l/∊0∊)/∂p].Comparing the Qh values of several rocksalt- and perovskite-type fluorides and oxides,a general empirical rule is proposed that the electrostrictive coefficient of fluorides is larger than that of oxides with the same crystal structure and the Qh of the rocksalt is larger than that of the perovskite. A simple shell model can describe this general tendency in conjunction with the Bom-Mayer potential,where the electrostrictive coefficient is represented in proportion to a5/Z2(a: cation-anion distance;Z:ionic valence).

Original languageEnglish (US)
Pages (from-to)1531-1535
Number of pages5
JournalJournal of the Physical Society of Japan
Volume53
Issue number4
DOIs
StatePublished - Jan 1 1984

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oxides
fluorides
coefficients
hydrostatic pressure
pressure dependence
proportion
tendencies
permittivity
anions
valence
cations
crystal structure

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

@article{a467267941f347b980154251de95cfd6,
title = "Electrostrictive Coefficient of a Rocksalt-Type Oxide MgO",
abstract = "The electric-displacement-related electrostrictive coefficient Qh of a rocksalt-type oxide, MgO, has been determined as 0.16 m4C-2 by measuring the hydrostatic pressure dependence of the reciprocal permittivity(Qh=(l/2)[∂(l/∊0∊)/∂p].Comparing the Qh values of several rocksalt- and perovskite-type fluorides and oxides,a general empirical rule is proposed that the electrostrictive coefficient of fluorides is larger than that of oxides with the same crystal structure and the Qh of the rocksalt is larger than that of the perovskite. A simple shell model can describe this general tendency in conjunction with the Bom-Mayer potential,where the electrostrictive coefficient is represented in proportion to a5/Z2(a: cation-anion distance;Z:ionic valence).",
author = "Kenji Uchino",
year = "1984",
month = "1",
day = "1",
doi = "10.1143/JPSJ.53.1531",
language = "English (US)",
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journal = "Journal of the Physical Society of Japan",
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Electrostrictive Coefficient of a Rocksalt-Type Oxide MgO. / Uchino, Kenji.

In: Journal of the Physical Society of Japan, Vol. 53, No. 4, 01.01.1984, p. 1531-1535.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Electrostrictive Coefficient of a Rocksalt-Type Oxide MgO

AU - Uchino, Kenji

PY - 1984/1/1

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N2 - The electric-displacement-related electrostrictive coefficient Qh of a rocksalt-type oxide, MgO, has been determined as 0.16 m4C-2 by measuring the hydrostatic pressure dependence of the reciprocal permittivity(Qh=(l/2)[∂(l/∊0∊)/∂p].Comparing the Qh values of several rocksalt- and perovskite-type fluorides and oxides,a general empirical rule is proposed that the electrostrictive coefficient of fluorides is larger than that of oxides with the same crystal structure and the Qh of the rocksalt is larger than that of the perovskite. A simple shell model can describe this general tendency in conjunction with the Bom-Mayer potential,where the electrostrictive coefficient is represented in proportion to a5/Z2(a: cation-anion distance;Z:ionic valence).

AB - The electric-displacement-related electrostrictive coefficient Qh of a rocksalt-type oxide, MgO, has been determined as 0.16 m4C-2 by measuring the hydrostatic pressure dependence of the reciprocal permittivity(Qh=(l/2)[∂(l/∊0∊)/∂p].Comparing the Qh values of several rocksalt- and perovskite-type fluorides and oxides,a general empirical rule is proposed that the electrostrictive coefficient of fluorides is larger than that of oxides with the same crystal structure and the Qh of the rocksalt is larger than that of the perovskite. A simple shell model can describe this general tendency in conjunction with the Bom-Mayer potential,where the electrostrictive coefficient is represented in proportion to a5/Z2(a: cation-anion distance;Z:ionic valence).

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