The biomimetic synthesis of sanguiin H-5 (1) was accomplished through the diastereoselective formation of the crucial biphenyl carbon-carbon bond between galloyl moieties at the O (2) and O (3) positions of an appropriately protected glucose-derived precursor. Furthermore, the /3-anomeric galloyl linkage was established with complete stereochemical control.
|Original language||English (US)|
|Number of pages||8|
|Journal||Journal of Organic Chemistry|
|State||Published - Dec 1 1995|
All Science Journal Classification (ASJC) codes
- Organic Chemistry