Enhanced ammonia adsorption on functionalized nanoporous carbons

Ali Qajar, Maryam Peer, Mohammad Reza Andalibi, Ramakrishnan Rajagopalan, Henry C. Foley

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Nanoporous carbons were synthesized and treated with nitric acid after which the change in their propensities for ammonia adsorption was determined. The adsorbents had mean pore sizes ranging from 0.5 to 12 nm and they included polyfurfuryl alcohol (PFA)-derived carbons, commercial activated carbons, and both soft and hard-templated mesoporous carbons. The carbons were treated with concentrated nitric acid at elevated temperatures (e.g. 90°C) and for time spans between 15 and 240 min. The textural properties of carbons, before and after nitric acid treatment, were determined using CO2 adsorption at 0°C. Ammonia adsorption uptakes were measured at 25°C and at pressures up to 9.5 bar. The highest total uptake of ammonia on the native carbons, that is prior to nitric acid treatment, was ∼10 mmol/g at 1 bar and 25°C; this was obtained on a microporous carbon derived from the pyrolysis of polyfurfuryl alcohol and polyethylene glycol blends followed by CO2 oxidation. Nitric acid treatment of this carbon significantly increased its total uptake of ammonia to 17 mmol/g. This sample provided a reversible uptake of 14 mmol/g after it was outgassed at 160°C and 10-5 bar under dynamic vacuum. This is 2 mmol/g higher than state-of-the-art ammonia adsorbents such as COF-10. An x-ray photoelectron spectrum (XPS) showed that the oxygen content of the carbon increased from 3 at.% to 16.4 at.% after the nitric acid treatment. Heats of adsorption profiles, calculated from adsorption isotherms, started from 165 kJ/mol and quickly dropped to 40 kJ/mol with ammonia loading. This showed that the isosteric heat of adsorption on the remaining surface was still higher than the native carbon sample resulting in high reversible adsorption uptake, even after excluding the irreversible adsorption on the very high energy sites.

Original languageEnglish (US)
Pages (from-to)15-23
Number of pages9
JournalMicroporous and Mesoporous Materials
Volume218
DOIs
StatePublished - Jul 20 2015

Fingerprint

Ammonia
ammonia
Carbon
Nitric Acid
Adsorption
nitric acid
Nitric acid
adsorption
carbon
adsorbents
Adsorbents
alcohols
Alcohols
heat
activated carbon
Photoelectrons
Adsorption isotherms
Activated carbon
Polyethylene glycols
Pore size

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

Cite this

Qajar, Ali ; Peer, Maryam ; Andalibi, Mohammad Reza ; Rajagopalan, Ramakrishnan ; Foley, Henry C. / Enhanced ammonia adsorption on functionalized nanoporous carbons. In: Microporous and Mesoporous Materials. 2015 ; Vol. 218. pp. 15-23.
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Enhanced ammonia adsorption on functionalized nanoporous carbons. / Qajar, Ali; Peer, Maryam; Andalibi, Mohammad Reza; Rajagopalan, Ramakrishnan; Foley, Henry C.

In: Microporous and Mesoporous Materials, Vol. 218, 20.07.2015, p. 15-23.

Research output: Contribution to journalArticle

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T1 - Enhanced ammonia adsorption on functionalized nanoporous carbons

AU - Qajar, Ali

AU - Peer, Maryam

AU - Andalibi, Mohammad Reza

AU - Rajagopalan, Ramakrishnan

AU - Foley, Henry C.

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AB - Nanoporous carbons were synthesized and treated with nitric acid after which the change in their propensities for ammonia adsorption was determined. The adsorbents had mean pore sizes ranging from 0.5 to 12 nm and they included polyfurfuryl alcohol (PFA)-derived carbons, commercial activated carbons, and both soft and hard-templated mesoporous carbons. The carbons were treated with concentrated nitric acid at elevated temperatures (e.g. 90°C) and for time spans between 15 and 240 min. The textural properties of carbons, before and after nitric acid treatment, were determined using CO2 adsorption at 0°C. Ammonia adsorption uptakes were measured at 25°C and at pressures up to 9.5 bar. The highest total uptake of ammonia on the native carbons, that is prior to nitric acid treatment, was ∼10 mmol/g at 1 bar and 25°C; this was obtained on a microporous carbon derived from the pyrolysis of polyfurfuryl alcohol and polyethylene glycol blends followed by CO2 oxidation. Nitric acid treatment of this carbon significantly increased its total uptake of ammonia to 17 mmol/g. This sample provided a reversible uptake of 14 mmol/g after it was outgassed at 160°C and 10-5 bar under dynamic vacuum. This is 2 mmol/g higher than state-of-the-art ammonia adsorbents such as COF-10. An x-ray photoelectron spectrum (XPS) showed that the oxygen content of the carbon increased from 3 at.% to 16.4 at.% after the nitric acid treatment. Heats of adsorption profiles, calculated from adsorption isotherms, started from 165 kJ/mol and quickly dropped to 40 kJ/mol with ammonia loading. This showed that the isosteric heat of adsorption on the remaining surface was still higher than the native carbon sample resulting in high reversible adsorption uptake, even after excluding the irreversible adsorption on the very high energy sites.

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