Enhanced electrocaloric effect in poly(vinylidene fluoride- trifluoroethylene)-based terpolymer/copolymer blends

Xiang Zhong Chen, Xiao Shi Qian, Xinyu Li, S. G. Lu, Hai Ming Gu, Minren Lin, Qun Dong Shen, Qiming Zhang

    Research output: Contribution to journalArticle

    24 Citations (Scopus)

    Abstract

    The electrocaloric effect in the blends of poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) with small amount of poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) is investigated. It was found that small amount of P(VDF-TrFE) (∼10 wt. ) can cause a more than 10 increase in the crystallinity in the blends. Although the two polymers form separate crystalline phases, the interfacial couplings to the random defects in the terpolymer convert the normal ferroelectric P(VDF-TrFE) into a relaxor ferroelectric. As a result, the blends with 10 wt. of P(VDF-TrFE) exhibit a 30 increase in the adiabatic temperature change over the entire experimental temperature range (20 °C-60 °C).

    Original languageEnglish (US)
    Article number222902
    JournalApplied Physics Letters
    Volume100
    Issue number22
    DOIs
    StatePublished - May 28 2012

    Fingerprint

    vinylidene
    fluorides
    copolymers
    crystallinity
    temperature
    causes
    defects
    polymers

    All Science Journal Classification (ASJC) codes

    • Physics and Astronomy (miscellaneous)

    Cite this

    Chen, Xiang Zhong ; Qian, Xiao Shi ; Li, Xinyu ; Lu, S. G. ; Gu, Hai Ming ; Lin, Minren ; Shen, Qun Dong ; Zhang, Qiming. / Enhanced electrocaloric effect in poly(vinylidene fluoride- trifluoroethylene)-based terpolymer/copolymer blends. In: Applied Physics Letters. 2012 ; Vol. 100, No. 22.
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    abstract = "The electrocaloric effect in the blends of poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) with small amount of poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) is investigated. It was found that small amount of P(VDF-TrFE) (∼10 wt. ) can cause a more than 10 increase in the crystallinity in the blends. Although the two polymers form separate crystalline phases, the interfacial couplings to the random defects in the terpolymer convert the normal ferroelectric P(VDF-TrFE) into a relaxor ferroelectric. As a result, the blends with 10 wt. of P(VDF-TrFE) exhibit a 30 increase in the adiabatic temperature change over the entire experimental temperature range (20 °C-60 °C).",
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    Enhanced electrocaloric effect in poly(vinylidene fluoride- trifluoroethylene)-based terpolymer/copolymer blends. / Chen, Xiang Zhong; Qian, Xiao Shi; Li, Xinyu; Lu, S. G.; Gu, Hai Ming; Lin, Minren; Shen, Qun Dong; Zhang, Qiming.

    In: Applied Physics Letters, Vol. 100, No. 22, 222902, 28.05.2012.

    Research output: Contribution to journalArticle

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    T1 - Enhanced electrocaloric effect in poly(vinylidene fluoride- trifluoroethylene)-based terpolymer/copolymer blends

    AU - Chen, Xiang Zhong

    AU - Qian, Xiao Shi

    AU - Li, Xinyu

    AU - Lu, S. G.

    AU - Gu, Hai Ming

    AU - Lin, Minren

    AU - Shen, Qun Dong

    AU - Zhang, Qiming

    PY - 2012/5/28

    Y1 - 2012/5/28

    N2 - The electrocaloric effect in the blends of poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) with small amount of poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) is investigated. It was found that small amount of P(VDF-TrFE) (∼10 wt. ) can cause a more than 10 increase in the crystallinity in the blends. Although the two polymers form separate crystalline phases, the interfacial couplings to the random defects in the terpolymer convert the normal ferroelectric P(VDF-TrFE) into a relaxor ferroelectric. As a result, the blends with 10 wt. of P(VDF-TrFE) exhibit a 30 increase in the adiabatic temperature change over the entire experimental temperature range (20 °C-60 °C).

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