Epitaxial graphene/silicon carbide intercalation: A minireview on graphene modulation and unique 2D materials

Natalie Briggs, Zewdu M. Gebeyehu, Alexander Vera, Tian Zhao, Ke Wang, Ana De La Fuente Duran, Brian Bersch, Timothy Bowen, Kenneth Knappenberger, Joshua Alexander Robinson

Research output: Contribution to journalReview article

1 Citation (Scopus)

Abstract

Intercalation of atomic species through epitaxial graphene on silicon carbide began only a few years following its initial report in 2004. The impact of intercalation on the electronic properties of the graphene is well known; however, the intercalant itself can also exhibit intriguing properties not found in nature. This realization has inspired new interest in epitaxial graphene/silicon carbide (EG/SiC) intercalation, where the scope of the technique extends beyond modulation of graphene properties to the creation of new 2D forms of 3D materials. The mission of this minireview is to provide a concise introduction to EG/SiC intercalation and to demonstrate a simplified approach to EG/SiC intercalation. We summarize the primary techniques used to achieve and characterize EG/SiC intercalation, and show that thermal evaporation-based methods can effectively substitute for more complex synthesis techniques, enabling large-scale intercalation of non-refractory metals and compounds including two-dimensional silver (2D-Ag) and gallium nitride (2D-GaNx).

Original languageEnglish (US)
Pages (from-to)15440-15447
Number of pages8
JournalNanoscale
Volume11
Issue number33
DOIs
StatePublished - Sep 7 2019

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Graphite
Intercalation
Silicon carbide
Graphene
Modulation
Gallium nitride
Thermal evaporation
silicon carbide
Silver
Electronic properties
Metals

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Briggs, Natalie ; Gebeyehu, Zewdu M. ; Vera, Alexander ; Zhao, Tian ; Wang, Ke ; De La Fuente Duran, Ana ; Bersch, Brian ; Bowen, Timothy ; Knappenberger, Kenneth ; Robinson, Joshua Alexander. / Epitaxial graphene/silicon carbide intercalation : A minireview on graphene modulation and unique 2D materials. In: Nanoscale. 2019 ; Vol. 11, No. 33. pp. 15440-15447.
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abstract = "Intercalation of atomic species through epitaxial graphene on silicon carbide began only a few years following its initial report in 2004. The impact of intercalation on the electronic properties of the graphene is well known; however, the intercalant itself can also exhibit intriguing properties not found in nature. This realization has inspired new interest in epitaxial graphene/silicon carbide (EG/SiC) intercalation, where the scope of the technique extends beyond modulation of graphene properties to the creation of new 2D forms of 3D materials. The mission of this minireview is to provide a concise introduction to EG/SiC intercalation and to demonstrate a simplified approach to EG/SiC intercalation. We summarize the primary techniques used to achieve and characterize EG/SiC intercalation, and show that thermal evaporation-based methods can effectively substitute for more complex synthesis techniques, enabling large-scale intercalation of non-refractory metals and compounds including two-dimensional silver (2D-Ag) and gallium nitride (2D-GaNx).",
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Briggs, N, Gebeyehu, ZM, Vera, A, Zhao, T, Wang, K, De La Fuente Duran, A, Bersch, B, Bowen, T, Knappenberger, K & Robinson, JA 2019, 'Epitaxial graphene/silicon carbide intercalation: A minireview on graphene modulation and unique 2D materials', Nanoscale, vol. 11, no. 33, pp. 15440-15447. https://doi.org/10.1039/c9nr03721g

Epitaxial graphene/silicon carbide intercalation : A minireview on graphene modulation and unique 2D materials. / Briggs, Natalie; Gebeyehu, Zewdu M.; Vera, Alexander; Zhao, Tian; Wang, Ke; De La Fuente Duran, Ana; Bersch, Brian; Bowen, Timothy; Knappenberger, Kenneth; Robinson, Joshua Alexander.

In: Nanoscale, Vol. 11, No. 33, 07.09.2019, p. 15440-15447.

Research output: Contribution to journalReview article

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T1 - Epitaxial graphene/silicon carbide intercalation

T2 - A minireview on graphene modulation and unique 2D materials

AU - Briggs, Natalie

AU - Gebeyehu, Zewdu M.

AU - Vera, Alexander

AU - Zhao, Tian

AU - Wang, Ke

AU - De La Fuente Duran, Ana

AU - Bersch, Brian

AU - Bowen, Timothy

AU - Knappenberger, Kenneth

AU - Robinson, Joshua Alexander

PY - 2019/9/7

Y1 - 2019/9/7

N2 - Intercalation of atomic species through epitaxial graphene on silicon carbide began only a few years following its initial report in 2004. The impact of intercalation on the electronic properties of the graphene is well known; however, the intercalant itself can also exhibit intriguing properties not found in nature. This realization has inspired new interest in epitaxial graphene/silicon carbide (EG/SiC) intercalation, where the scope of the technique extends beyond modulation of graphene properties to the creation of new 2D forms of 3D materials. The mission of this minireview is to provide a concise introduction to EG/SiC intercalation and to demonstrate a simplified approach to EG/SiC intercalation. We summarize the primary techniques used to achieve and characterize EG/SiC intercalation, and show that thermal evaporation-based methods can effectively substitute for more complex synthesis techniques, enabling large-scale intercalation of non-refractory metals and compounds including two-dimensional silver (2D-Ag) and gallium nitride (2D-GaNx).

AB - Intercalation of atomic species through epitaxial graphene on silicon carbide began only a few years following its initial report in 2004. The impact of intercalation on the electronic properties of the graphene is well known; however, the intercalant itself can also exhibit intriguing properties not found in nature. This realization has inspired new interest in epitaxial graphene/silicon carbide (EG/SiC) intercalation, where the scope of the technique extends beyond modulation of graphene properties to the creation of new 2D forms of 3D materials. The mission of this minireview is to provide a concise introduction to EG/SiC intercalation and to demonstrate a simplified approach to EG/SiC intercalation. We summarize the primary techniques used to achieve and characterize EG/SiC intercalation, and show that thermal evaporation-based methods can effectively substitute for more complex synthesis techniques, enabling large-scale intercalation of non-refractory metals and compounds including two-dimensional silver (2D-Ag) and gallium nitride (2D-GaNx).

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