Equilibrium phase behavior of polyethylene oxide and of its mixtures with tetrahydronaphthalene or/and poly(ethylene oxide-block-dimethylsiloxane)

Samy A. Madbouly, Bernhard A. Wolf

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The measurement of the light transmitted through the systems as a function of T at different constant cooling or heating rates q has proven very useful for the investigation of phase equilibria in the case of systems that contain crystallizable polymers. For PEO it is demonstrated that equilibrium melting temperature sare experimentally accessible in contrast to general belief. To which extent this statement also holds true for polymers of a complex structure requires further experiments.

Original languageEnglish (US)
Pages (from-to)7357-7363
Number of pages7
JournalJournal of Chemical Physics
Volume117
Issue number15
DOIs
StatePublished - Oct 15 2002

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Tetrahydronaphthalenes
Dimethylpolysiloxanes
Phase behavior
ethylene oxide
Polyethylene oxides
polyethylenes
Polymers
oxides
polymers
Heating rate
Phase equilibria
Melting point
melting
Cooling
cooling
heating
Experiments
temperature

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

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