Estimation and modeling of coal pore accessibility using small angle neutron scattering

Rui Zhang, Shimin Liu, Jitendra Bahadur, Derek Elsworth, Yuri Melnichenko, Lilin He, Yi Wang

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Gas diffusion in coal is controlled by nano-structure of the pores. The interconnectivity of pores not only determines the dynamics of gas transport in the coal matrix but also influences the mechanical strength. In this study, small angle neutron scattering (SANS) was employed to quantify pore accessibility for two coal samples, one of sub-bituminous rank and the other of anthracite rank. A theoretical pore accessibility model was proposed based on scattering intensities under both vacuum and zero average contrast (ZAC) conditions. The results show that scattering intensity decreases with increasing gas pressure using deuterated methane (CD4) at low Q values for both coals. Pores smaller than 40 nm in radius are less accessible for anthracite than sub-bituminous coal. On the contrary, when the pore radius is larger than 40 nm, the pore accessibility of anthracite becomes larger than that of sub-bituminous coal. Only 20% of pores are accessible to CD4 for anthracite and 37% for sub-bituminous coal, where the pore radius is 16 nm. For these two coals, pore accessibility and pore radius follows a power-law relationship.

Original languageEnglish (US)
Pages (from-to)323-332
Number of pages10
JournalFuel
Volume161
DOIs
StatePublished - Dec 1 2015

Fingerprint

Coal
Neutron scattering
Anthracite
Bituminous coal
Scattering
Diffusion in gases
Gases
Strength of materials
Methane
Vacuum

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Organic Chemistry

Cite this

Zhang, Rui ; Liu, Shimin ; Bahadur, Jitendra ; Elsworth, Derek ; Melnichenko, Yuri ; He, Lilin ; Wang, Yi. / Estimation and modeling of coal pore accessibility using small angle neutron scattering. In: Fuel. 2015 ; Vol. 161. pp. 323-332.
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abstract = "Gas diffusion in coal is controlled by nano-structure of the pores. The interconnectivity of pores not only determines the dynamics of gas transport in the coal matrix but also influences the mechanical strength. In this study, small angle neutron scattering (SANS) was employed to quantify pore accessibility for two coal samples, one of sub-bituminous rank and the other of anthracite rank. A theoretical pore accessibility model was proposed based on scattering intensities under both vacuum and zero average contrast (ZAC) conditions. The results show that scattering intensity decreases with increasing gas pressure using deuterated methane (CD4) at low Q values for both coals. Pores smaller than 40 nm in radius are less accessible for anthracite than sub-bituminous coal. On the contrary, when the pore radius is larger than 40 nm, the pore accessibility of anthracite becomes larger than that of sub-bituminous coal. Only 20{\%} of pores are accessible to CD4 for anthracite and 37{\%} for sub-bituminous coal, where the pore radius is 16 nm. For these two coals, pore accessibility and pore radius follows a power-law relationship.",
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Estimation and modeling of coal pore accessibility using small angle neutron scattering. / Zhang, Rui; Liu, Shimin; Bahadur, Jitendra; Elsworth, Derek; Melnichenko, Yuri; He, Lilin; Wang, Yi.

In: Fuel, Vol. 161, 01.12.2015, p. 323-332.

Research output: Contribution to journalArticle

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AU - Zhang, Rui

AU - Liu, Shimin

AU - Bahadur, Jitendra

AU - Elsworth, Derek

AU - Melnichenko, Yuri

AU - He, Lilin

AU - Wang, Yi

PY - 2015/12/1

Y1 - 2015/12/1

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AB - Gas diffusion in coal is controlled by nano-structure of the pores. The interconnectivity of pores not only determines the dynamics of gas transport in the coal matrix but also influences the mechanical strength. In this study, small angle neutron scattering (SANS) was employed to quantify pore accessibility for two coal samples, one of sub-bituminous rank and the other of anthracite rank. A theoretical pore accessibility model was proposed based on scattering intensities under both vacuum and zero average contrast (ZAC) conditions. The results show that scattering intensity decreases with increasing gas pressure using deuterated methane (CD4) at low Q values for both coals. Pores smaller than 40 nm in radius are less accessible for anthracite than sub-bituminous coal. On the contrary, when the pore radius is larger than 40 nm, the pore accessibility of anthracite becomes larger than that of sub-bituminous coal. Only 20% of pores are accessible to CD4 for anthracite and 37% for sub-bituminous coal, where the pore radius is 16 nm. For these two coals, pore accessibility and pore radius follows a power-law relationship.

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