(Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III)

Lin Cheng, Nan Xu, Douglas R. Powell, George B. Richter-Addo

Research output: Contribution to journalArticle

Abstract

The title compound, [Fe(C2H5O)(C36H 44N4)], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe - Np distance is 2.078 (2) Å and the Fe - O distance is 1.8232 (18) Å. The eth-oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe - O - C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.

Original languageEnglish (US)
Pages (from-to)m1458
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number11
DOIs
StatePublished - Nov 1 2010

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Iron
iron
Atoms
Porphyrins
porphyrins
atoms
Ligands
ligands
linkages

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Cheng, Lin ; Xu, Nan ; Powell, Douglas R. ; Richter-Addo, George B. / (Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III). In: Acta Crystallographica Section E: Structure Reports Online. 2010 ; Vol. 66, No. 11. pp. m1458.
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abstract = "The title compound, [Fe(C2H5O)(C36H 44N4)], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504 (2) {\AA} towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe - Np distance is 2.078 (2) {\AA} and the Fe - O distance is 1.8232 (18) {\AA}. The eth-oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe - O - C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.",
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(Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III). / Cheng, Lin; Xu, Nan; Powell, Douglas R.; Richter-Addo, George B.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 11, 01.11.2010, p. m1458.

Research output: Contribution to journalArticle

TY - JOUR

T1 - (Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III)

AU - Cheng, Lin

AU - Xu, Nan

AU - Powell, Douglas R.

AU - Richter-Addo, George B.

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AB - The title compound, [Fe(C2H5O)(C36H 44N4)], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe - Np distance is 2.078 (2) Å and the Fe - O distance is 1.8232 (18) Å. The eth-oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe - O - C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.

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