Evaluating ligands for use in polymer ligand film (PLF) for plutonium and uranium extraction

Jung H. Rim, Dominic S. Peterson, Claudine E. Armenta, Edward R. Gonzales, Kenan Ünlü

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

This paper describes a new analyte extraction technique using polymer ligand film (PLF). PLFs were synthesized to perform direct sorption of analytes onto its surface for direct counting using alpha spectroscopy. The main focus of the new technique is to shorten and simplify the procedure for chemically isolating radionuclides for determination through a radiometric technique. 4′(5′)-di-t-butylcyclohexano 18-crown-6 (DtBuCH18C6) and 2-ethylhexylphosphonic acid (HEH[EHP]) were examined for plutonium extraction. Di(2-ethyl hexyl) phosphoric acid (HDEHP) were examined for plutonium and uranium extraction. DtBuCH18C6 and HEH[EHP] were not effective in plutonium extraction. HDEHP PLFs were effective for plutonium but not for uranium.

Original languageEnglish (US)
Pages (from-to)193-198
Number of pages6
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume305
Issue number1
DOIs
StatePublished - Jul 8 2015

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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