Evidence of degradation of polybrominated biphenyls in soil samples from michigan

Robert H. Hill, Donald G. Patterson, Donna L. Orti, James S. Holler, Larry L. Needham, Sandra L. Sirmans, John A. Liddle

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Soil samples obtained from the former polybrominated biphenyls (PBB) manufacturing site in Michigan were analyzed by gas chromatography and gas chromatography with mass spectrometric detection. The results indicate significant degradation of, the PBB residue in the soil sample. The soil sample with the highest concentration of PBB has the greatest degree of degradation. Principal degradation products include 2,3',4,4’,5-pentabromobiphenyl, 2,2',4,4’,5-pentabromobiphenyl and two unidentified tetrab romobipheny1s, The degradation pattern observed supports a photochemical decomposition mechanism. These degraded residues may be more toxic than the original Firemaster residues. The implications of the results are discussed.

Original languageEnglish (US)
Pages (from-to)19-33
Number of pages15
JournalJournal of Environmental Science and Health, Part B
Volume17
Issue number1
DOIs
StatePublished - Jan 1 1982

All Science Journal Classification (ASJC) codes

  • Food Science
  • Pollution

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