Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates

Jay C. Amicangelo, Willem R. Leenstra

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.

Original languageEnglish (US)
Pages (from-to)14698-14699
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number48
DOIs
StatePublished - Dec 3 2003

Fingerprint

Organophosphonates
Chromophores
Zirconium
Fluorescence
Anthracene
Naphthalene
Monomers
anthracene
naphthalene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

@article{3f432e6fe0af49ea8edf2f250e4fa33f,
title = "Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates",
abstract = "Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.",
author = "Amicangelo, {Jay C.} and Leenstra, {Willem R.}",
year = "2003",
month = "12",
day = "3",
doi = "10.1021/ja030483h",
language = "English (US)",
volume = "125",
pages = "14698--14699",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "48",

}

Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates. / Amicangelo, Jay C.; Leenstra, Willem R.

In: Journal of the American Chemical Society, Vol. 125, No. 48, 03.12.2003, p. 14698-14699.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates

AU - Amicangelo, Jay C.

AU - Leenstra, Willem R.

PY - 2003/12/3

Y1 - 2003/12/3

N2 - Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.

AB - Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.

UR - http://www.scopus.com/inward/record.url?scp=0345293189&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0345293189&partnerID=8YFLogxK

U2 - 10.1021/ja030483h

DO - 10.1021/ja030483h

M3 - Article

C2 - 14640632

AN - SCOPUS:0345293189

VL - 125

SP - 14698

EP - 14699

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 48

ER -