Excited-state proton transfer and hydrogen-bonding dynamics in 7-azaindole: time-resolved fluorescence and computer simulation

C. F. Chapman, T. J. Marrone, R. S. Moog, M. Maroncelli

Research output: Chapter in Book/Report/Conference proceedingChapter

3 Scopus citations

Abstract

We recently measured complete time- and frequency-resolved fluorescence spectra of 7AI in a number of alcohols and showed how past ambiguities could be traced to the fact that the ″normal″ fluorescence undergoes a time-dependent Stokes shift. This Stokes shift is a result of solvation energy relaxation and is not directly connected to the population kinetics of the reaction. We also have performed an extensive series of measurements of the proton transfer rate of 7AI as a function of alcohol, temperature, and solvent deuteration.

Original languageEnglish (US)
Title of host publicationUltrafast Phenomena VIII
PublisherPubl by Springer-Verlag GmbH & Company KG
Pages624-625
Number of pages2
Edition55
ISBN (Print)3540564756
StatePublished - Jan 1 1993
EventProceedings of the 8th International Conference on Ultrafast Phenomena - Antibes Juan-Les-Pins, France
Duration: Jun 8 1992Jun 12 1992

Conference

ConferenceProceedings of the 8th International Conference on Ultrafast Phenomena
CityAntibes Juan-Les-Pins, France
Period6/8/926/12/92

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry

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