Exposure to nanoscale particles and fibers during machining of hybrid advanced composites containing carbon nanotubes

Dhimiter Bello, Brian L. Wardle, Namiko Yamamoto, Roberto Guzman DeVilloria, Enrique J. Garcia, Anastasios J. Hart, Kwangseog Ahn, Michael J. Ellenbecker, Marilyn Hallock

Research output: Contribution to journalArticle

193 Citations (Scopus)

Abstract

This study investigated airborne exposures to nanoscale particles and fibers generated during dry and wet abrasive machining of two three-phase advanced composite systems containing carbon nanotubes (CNTs), micron-diameter continuous fibers (carbon or alumina), and thermoset polymer matrices. Exposures were evaluated with a suite of complementary instruments, including real-time particle number concentration and size distribution (0.005-20 μm), electron microscopy, and integrated sampling for fibers and respirable particulate at the source and breathing zone of the operator. Wet cutting, the usual procedure for such composites, did not produce exposures significantly different than background whereas dry cutting, without any emissions controls, provided a worst-case exposure and this article focuses here. Overall particle release levels, peaks in the size distribution of the particles, and surface area of released particles (including size distribution) were not significantly different for composites with and without CNTs. The majority of released particle surface area originated from the respirable (1-10 μm) fraction, whereas the nano fraction contributed ∼10% of the surface area. CNTs, either individual or in bundles, were not observed in extensive electron microscopy of collected samples. The mean number concentration of peaks for dry cutting was composite dependent and varied over an order of magnitude with highest values for thicker laminates at the source being >1 × 106 particles cm-3. Concentration of respirable fibers for dry cutting at the source ranged from 2 to 4 fibers cm-3 depending on the composite type. Further investigation is required and underway to determine the effects of various exposure determinants, such as specimen and tool geometry, on particle release and effectiveness of controls.

Original languageEnglish (US)
Pages (from-to)231-249
Number of pages19
JournalJournal of Nanoparticle Research
Volume11
Issue number1
DOIs
StatePublished - Jan 1 2009

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Carbon Nanotubes
Nanotubes
Machining
machining
Carbon nanotubes
Carbon
carbon nanotubes
Composite
Fiber
composite materials
fibers
Fibers
Composite materials
Electron microscopy
Surface area
Electron Microscopy
Aluminum Oxide
Thermosets
Emission control
Polymer matrix

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Atomic and Molecular Physics, and Optics
  • Modeling and Simulation
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Bello, Dhimiter ; Wardle, Brian L. ; Yamamoto, Namiko ; Guzman DeVilloria, Roberto ; Garcia, Enrique J. ; Hart, Anastasios J. ; Ahn, Kwangseog ; Ellenbecker, Michael J. ; Hallock, Marilyn. / Exposure to nanoscale particles and fibers during machining of hybrid advanced composites containing carbon nanotubes. In: Journal of Nanoparticle Research. 2009 ; Vol. 11, No. 1. pp. 231-249.
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abstract = "This study investigated airborne exposures to nanoscale particles and fibers generated during dry and wet abrasive machining of two three-phase advanced composite systems containing carbon nanotubes (CNTs), micron-diameter continuous fibers (carbon or alumina), and thermoset polymer matrices. Exposures were evaluated with a suite of complementary instruments, including real-time particle number concentration and size distribution (0.005-20 μm), electron microscopy, and integrated sampling for fibers and respirable particulate at the source and breathing zone of the operator. Wet cutting, the usual procedure for such composites, did not produce exposures significantly different than background whereas dry cutting, without any emissions controls, provided a worst-case exposure and this article focuses here. Overall particle release levels, peaks in the size distribution of the particles, and surface area of released particles (including size distribution) were not significantly different for composites with and without CNTs. The majority of released particle surface area originated from the respirable (1-10 μm) fraction, whereas the nano fraction contributed ∼10{\%} of the surface area. CNTs, either individual or in bundles, were not observed in extensive electron microscopy of collected samples. The mean number concentration of peaks for dry cutting was composite dependent and varied over an order of magnitude with highest values for thicker laminates at the source being >1 × 106 particles cm-3. Concentration of respirable fibers for dry cutting at the source ranged from 2 to 4 fibers cm-3 depending on the composite type. Further investigation is required and underway to determine the effects of various exposure determinants, such as specimen and tool geometry, on particle release and effectiveness of controls.",
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Bello, D, Wardle, BL, Yamamoto, N, Guzman DeVilloria, R, Garcia, EJ, Hart, AJ, Ahn, K, Ellenbecker, MJ & Hallock, M 2009, 'Exposure to nanoscale particles and fibers during machining of hybrid advanced composites containing carbon nanotubes', Journal of Nanoparticle Research, vol. 11, no. 1, pp. 231-249. https://doi.org/10.1007/s11051-008-9499-4

Exposure to nanoscale particles and fibers during machining of hybrid advanced composites containing carbon nanotubes. / Bello, Dhimiter; Wardle, Brian L.; Yamamoto, Namiko; Guzman DeVilloria, Roberto; Garcia, Enrique J.; Hart, Anastasios J.; Ahn, Kwangseog; Ellenbecker, Michael J.; Hallock, Marilyn.

In: Journal of Nanoparticle Research, Vol. 11, No. 1, 01.01.2009, p. 231-249.

Research output: Contribution to journalArticle

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AU - Bello, Dhimiter

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N2 - This study investigated airborne exposures to nanoscale particles and fibers generated during dry and wet abrasive machining of two three-phase advanced composite systems containing carbon nanotubes (CNTs), micron-diameter continuous fibers (carbon or alumina), and thermoset polymer matrices. Exposures were evaluated with a suite of complementary instruments, including real-time particle number concentration and size distribution (0.005-20 μm), electron microscopy, and integrated sampling for fibers and respirable particulate at the source and breathing zone of the operator. Wet cutting, the usual procedure for such composites, did not produce exposures significantly different than background whereas dry cutting, without any emissions controls, provided a worst-case exposure and this article focuses here. Overall particle release levels, peaks in the size distribution of the particles, and surface area of released particles (including size distribution) were not significantly different for composites with and without CNTs. The majority of released particle surface area originated from the respirable (1-10 μm) fraction, whereas the nano fraction contributed ∼10% of the surface area. CNTs, either individual or in bundles, were not observed in extensive electron microscopy of collected samples. The mean number concentration of peaks for dry cutting was composite dependent and varied over an order of magnitude with highest values for thicker laminates at the source being >1 × 106 particles cm-3. Concentration of respirable fibers for dry cutting at the source ranged from 2 to 4 fibers cm-3 depending on the composite type. Further investigation is required and underway to determine the effects of various exposure determinants, such as specimen and tool geometry, on particle release and effectiveness of controls.

AB - This study investigated airborne exposures to nanoscale particles and fibers generated during dry and wet abrasive machining of two three-phase advanced composite systems containing carbon nanotubes (CNTs), micron-diameter continuous fibers (carbon or alumina), and thermoset polymer matrices. Exposures were evaluated with a suite of complementary instruments, including real-time particle number concentration and size distribution (0.005-20 μm), electron microscopy, and integrated sampling for fibers and respirable particulate at the source and breathing zone of the operator. Wet cutting, the usual procedure for such composites, did not produce exposures significantly different than background whereas dry cutting, without any emissions controls, provided a worst-case exposure and this article focuses here. Overall particle release levels, peaks in the size distribution of the particles, and surface area of released particles (including size distribution) were not significantly different for composites with and without CNTs. The majority of released particle surface area originated from the respirable (1-10 μm) fraction, whereas the nano fraction contributed ∼10% of the surface area. CNTs, either individual or in bundles, were not observed in extensive electron microscopy of collected samples. The mean number concentration of peaks for dry cutting was composite dependent and varied over an order of magnitude with highest values for thicker laminates at the source being >1 × 106 particles cm-3. Concentration of respirable fibers for dry cutting at the source ranged from 2 to 4 fibers cm-3 depending on the composite type. Further investigation is required and underway to determine the effects of various exposure determinants, such as specimen and tool geometry, on particle release and effectiveness of controls.

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